Cargando…
Bis[N′-(9H-fluoren-9-ylidene)benzohydrazidato-κ(2) N′,O]copper(II)
In the title complex, [Cu(C(20)H(13)N(2)O)(2)], the Cu(II) ion is tetra-coordinated by an N(2)O(2) set of two ligands in a distorted rectangular-planar geometry. The dihedral angle between the two coordinated five-membered metalla rings is 37.5 (3)°. The molecular configuration is stabilized by tw...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246919/ https://www.ncbi.nlm.nih.gov/pubmed/22219739 http://dx.doi.org/10.1107/S1600536811038931 |
Sumario: | In the title complex, [Cu(C(20)H(13)N(2)O)(2)], the Cu(II) ion is tetra-coordinated by an N(2)O(2) set of two ligands in a distorted rectangular-planar geometry. The dihedral angle between the two coordinated five-membered metalla rings is 37.5 (3)°. The molecular configuration is stabilized by two C—H⋯O and two C—H⋯N intramolecular hydrogen bonds. The crystal packing is dominated by van der Waals interactions. Three atoms of the phenyl ring of the benzohydrazidate moiety are disordered over two sets of sites in a 0.625 (18):0.375 (18) ratio. |
---|