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Bis[N′-(9H-fluoren-9-yl­idene)benzohydrazidato-κ(2) N′,O]copper(II)

In the title complex, [Cu(C(20)H(13)N(2)O)(2)], the Cu(II) ion is tetra-coordinated by an N(2)O(2) set of two ligands in a distorted recta­ngular-planar geometry. The dihedral angle between the two coordinated five-membered metalla rings is 37.5 (3)°. The mol­ecular configuration is stabilized by tw...

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Detalles Bibliográficos
Autores principales: Guo, Yan-Ling, Dou, Wei, Liu, Wei-Sheng, Zhang, Hong-Rui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246919/
https://www.ncbi.nlm.nih.gov/pubmed/22219739
http://dx.doi.org/10.1107/S1600536811038931
Descripción
Sumario:In the title complex, [Cu(C(20)H(13)N(2)O)(2)], the Cu(II) ion is tetra-coordinated by an N(2)O(2) set of two ligands in a distorted recta­ngular-planar geometry. The dihedral angle between the two coordinated five-membered metalla rings is 37.5 (3)°. The mol­ecular configuration is stabilized by two C—H⋯O and two C—H⋯N intra­molecular hydrogen bonds. The crystal packing is dominated by van der Waals inter­actions. Three atoms of the phenyl ring of the benzohydrazidate moiety are disordered over two sets of sites in a 0.625 (18):0.375 (18) ratio.