Bis[N′-(9H-fluoren-9-yl­idene)benzohydrazidato-κ(2) N′,O]copper(II)

In the title complex, [Cu(C(20)H(13)N(2)O)(2)], the Cu(II) ion is tetra-coordinated by an N(2)O(2) set of two ligands in a distorted recta­ngular-planar geometry. The dihedral angle between the two coordinated five-membered metalla rings is 37.5 (3)°. The mol­ecular configuration is stabilized by tw...

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Detalles Bibliográficos
Autores principales: Guo, Yan-Ling, Dou, Wei, Liu, Wei-Sheng, Zhang, Hong-Rui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246919/
https://www.ncbi.nlm.nih.gov/pubmed/22219739
http://dx.doi.org/10.1107/S1600536811038931
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author Guo, Yan-Ling
Dou, Wei
Liu, Wei-Sheng
Zhang, Hong-Rui
author_facet Guo, Yan-Ling
Dou, Wei
Liu, Wei-Sheng
Zhang, Hong-Rui
author_sort Guo, Yan-Ling
collection PubMed
description In the title complex, [Cu(C(20)H(13)N(2)O)(2)], the Cu(II) ion is tetra-coordinated by an N(2)O(2) set of two ligands in a distorted recta­ngular-planar geometry. The dihedral angle between the two coordinated five-membered metalla rings is 37.5 (3)°. The mol­ecular configuration is stabilized by two C—H⋯O and two C—H⋯N intra­molecular hydrogen bonds. The crystal packing is dominated by van der Waals inter­actions. Three atoms of the phenyl ring of the benzohydrazidate moiety are disordered over two sets of sites in a 0.625 (18):0.375 (18) ratio.
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spelling pubmed-32469192012-01-04 Bis[N′-(9H-fluoren-9-yl­idene)benzohydrazidato-κ(2) N′,O]copper(II) Guo, Yan-Ling Dou, Wei Liu, Wei-Sheng Zhang, Hong-Rui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(20)H(13)N(2)O)(2)], the Cu(II) ion is tetra-coordinated by an N(2)O(2) set of two ligands in a distorted recta­ngular-planar geometry. The dihedral angle between the two coordinated five-membered metalla rings is 37.5 (3)°. The mol­ecular configuration is stabilized by two C—H⋯O and two C—H⋯N intra­molecular hydrogen bonds. The crystal packing is dominated by van der Waals inter­actions. Three atoms of the phenyl ring of the benzohydrazidate moiety are disordered over two sets of sites in a 0.625 (18):0.375 (18) ratio. International Union of Crystallography 2011-10-05 /pmc/articles/PMC3246919/ /pubmed/22219739 http://dx.doi.org/10.1107/S1600536811038931 Text en © Guo et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guo, Yan-Ling
Dou, Wei
Liu, Wei-Sheng
Zhang, Hong-Rui
Bis[N′-(9H-fluoren-9-yl­idene)benzohydrazidato-κ(2) N′,O]copper(II)
title Bis[N′-(9H-fluoren-9-yl­idene)benzohydrazidato-κ(2) N′,O]copper(II)
title_full Bis[N′-(9H-fluoren-9-yl­idene)benzohydrazidato-κ(2) N′,O]copper(II)
title_fullStr Bis[N′-(9H-fluoren-9-yl­idene)benzohydrazidato-κ(2) N′,O]copper(II)
title_full_unstemmed Bis[N′-(9H-fluoren-9-yl­idene)benzohydrazidato-κ(2) N′,O]copper(II)
title_short Bis[N′-(9H-fluoren-9-yl­idene)benzohydrazidato-κ(2) N′,O]copper(II)
title_sort bis[n′-(9h-fluoren-9-yl­idene)benzohydrazidato-κ(2) n′,o]copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246919/
https://www.ncbi.nlm.nih.gov/pubmed/22219739
http://dx.doi.org/10.1107/S1600536811038931
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AT liuweisheng bisn9hfluoren9ylidenebenzohydrazidatok2nocopperii
AT zhanghongrui bisn9hfluoren9ylidenebenzohydrazidatok2nocopperii

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