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Bis[bis(1H-pyrazol-1-yl)methane-κ(2) N (2),N (2′)](formato-κ(2) O,O′)copper(II) perchlorate
In the crystal structure of the title compound, [Cu(HCO(2))(C(7)H(8)N(4))(2)]ClO(4), the Cu(II) ion is octahedrally coordinated by one bidentate formate ion and two bidentate bis(1H-pyrazol-1-yl)methane ligands. There are C—H⋯O hydrogen bonds and π–π interactions [centroid–centroid distance = 3.4...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246920/ https://www.ncbi.nlm.nih.gov/pubmed/22219740 http://dx.doi.org/10.1107/S1600536811039675 |
| _version_ | 1782220004341579776 |
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| author | Zhao, Cai-Juan Zhang, Rui-Feng |
| author_facet | Zhao, Cai-Juan Zhang, Rui-Feng |
| author_sort | Zhao, Cai-Juan |
| collection | PubMed |
| description | In the crystal structure of the title compound, [Cu(HCO(2))(C(7)H(8)N(4))(2)]ClO(4), the Cu(II) ion is octahedrally coordinated by one bidentate formate ion and two bidentate bis(1H-pyrazol-1-yl)methane ligands. There are C—H⋯O hydrogen bonds and π–π interactions [centroid–centroid distance = 3.487 (3) Å] in the crystal structure. The perchlorate anion is disordered over two positions with an occupancy ratio of 0.628 (9):0.372 (9). |
| format | Online Article Text |
| id | pubmed-3246920 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32469202012-01-04 Bis[bis(1H-pyrazol-1-yl)methane-κ(2) N (2),N (2′)](formato-κ(2) O,O′)copper(II) perchlorate Zhao, Cai-Juan Zhang, Rui-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Cu(HCO(2))(C(7)H(8)N(4))(2)]ClO(4), the Cu(II) ion is octahedrally coordinated by one bidentate formate ion and two bidentate bis(1H-pyrazol-1-yl)methane ligands. There are C—H⋯O hydrogen bonds and π–π interactions [centroid–centroid distance = 3.487 (3) Å] in the crystal structure. The perchlorate anion is disordered over two positions with an occupancy ratio of 0.628 (9):0.372 (9). International Union of Crystallography 2011-10-05 /pmc/articles/PMC3246920/ /pubmed/22219740 http://dx.doi.org/10.1107/S1600536811039675 Text en © Zhao and Zhang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhao, Cai-Juan Zhang, Rui-Feng Bis[bis(1H-pyrazol-1-yl)methane-κ(2) N (2),N (2′)](formato-κ(2) O,O′)copper(II) perchlorate |
| title | Bis[bis(1H-pyrazol-1-yl)methane-κ(2)
N
(2),N
(2′)](formato-κ(2)
O,O′)copper(II) perchlorate |
| title_full | Bis[bis(1H-pyrazol-1-yl)methane-κ(2)
N
(2),N
(2′)](formato-κ(2)
O,O′)copper(II) perchlorate |
| title_fullStr | Bis[bis(1H-pyrazol-1-yl)methane-κ(2)
N
(2),N
(2′)](formato-κ(2)
O,O′)copper(II) perchlorate |
| title_full_unstemmed | Bis[bis(1H-pyrazol-1-yl)methane-κ(2)
N
(2),N
(2′)](formato-κ(2)
O,O′)copper(II) perchlorate |
| title_short | Bis[bis(1H-pyrazol-1-yl)methane-κ(2)
N
(2),N
(2′)](formato-κ(2)
O,O′)copper(II) perchlorate |
| title_sort | bis[bis(1h-pyrazol-1-yl)methane-κ(2)
n
(2),n
(2′)](formato-κ(2)
o,o′)copper(ii) perchlorate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246920/ https://www.ncbi.nlm.nih.gov/pubmed/22219740 http://dx.doi.org/10.1107/S1600536811039675 |
| work_keys_str_mv | AT zhaocaijuan bisbis1hpyrazol1ylmethanek2n2n2formatok2oocopperiiperchlorate AT zhangruifeng bisbis1hpyrazol1ylmethanek2n2n2formatok2oocopperiiperchlorate |