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Poly[bis(N,N-dimethylacetamide)-1κO,2κO-bis(μ(4)-thiophene-2,5-dicarboxylato-1:2:1′:2′κ(4) O (2):O (2′):O (5):O (5′))dizinc]
In the title polymeric complex, [Zn(2)(C(6)H(2)O(4)S)(2)(C(4)H(9)NO)(2)](n), each carboxylate group of the thiophene-2,5-dicarboxylate dianion bridges a pair of inversion-related dimethylacetamide-coordinated Zn(II) atoms, generating a layer motif parallel to (101). The Zn(II) atom shows a disto...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246922/ https://www.ncbi.nlm.nih.gov/pubmed/22219742 http://dx.doi.org/10.1107/S160053681103981X |
Sumario: | In the title polymeric complex, [Zn(2)(C(6)H(2)O(4)S)(2)(C(4)H(9)NO)(2)](n), each carboxylate group of the thiophene-2,5-dicarboxylate dianion bridges a pair of inversion-related dimethylacetamide-coordinated Zn(II) atoms, generating a layer motif parallel to (101). The Zn(II) atom shows a distorted square-pyramidal coordination; the apical site is occupied by the O atom of the dimethylacetamide molecule, whereas the four basal sites are occupied by carboxylate O atoms. In the crystal, the dimethylacetamide molecule is disordered over two positions in a 0.72 (1):0.28 (1) ratio in respect of the C atoms. |
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