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Poly[bis­(N,N-dimethyl­acetamide)-1κO,2κO-bis­(μ(4)-thio­phene-2,5-di­car­boxyl­ato-1:2:1′:2′κ(4) O (2):O (2′):O (5):O (5′))dizinc]

In the title polymeric complex, [Zn(2)(C(6)H(2)O(4)S)(2)(C(4)H(9)NO)(2)](n), each carboxyl­ate group of the thio­phene-2,5-dicarboxyl­ate dianion bridges a pair of inversion-related dimethyl­acetamide-coordinated Zn(II) atoms, generating a layer motif parallel to (101). The Zn(II) atom shows a disto...

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Detalles Bibliográficos
Autores principales: Du, Ming-Ming, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246922/
https://www.ncbi.nlm.nih.gov/pubmed/22219742
http://dx.doi.org/10.1107/S160053681103981X
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author Du, Ming-Ming
Ng, Seik Weng
author_facet Du, Ming-Ming
Ng, Seik Weng
author_sort Du, Ming-Ming
collection PubMed
description In the title polymeric complex, [Zn(2)(C(6)H(2)O(4)S)(2)(C(4)H(9)NO)(2)](n), each carboxyl­ate group of the thio­phene-2,5-dicarboxyl­ate dianion bridges a pair of inversion-related dimethyl­acetamide-coordinated Zn(II) atoms, generating a layer motif parallel to (101). The Zn(II) atom shows a distorted square-pyramidal coordination; the apical site is occupied by the O atom of the dimethyl­acetamide mol­ecule, whereas the four basal sites are occupied by carboxyl­ate O atoms. In the crystal, the dimethyl­acetamide mol­ecule is disordered over two positions in a 0.72 (1):0.28 (1) ratio in respect of the C atoms.
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spelling pubmed-32469222012-01-04 Poly[bis­(N,N-dimethyl­acetamide)-1κO,2κO-bis­(μ(4)-thio­phene-2,5-di­car­boxyl­ato-1:2:1′:2′κ(4) O (2):O (2′):O (5):O (5′))dizinc] Du, Ming-Ming Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title polymeric complex, [Zn(2)(C(6)H(2)O(4)S)(2)(C(4)H(9)NO)(2)](n), each carboxyl­ate group of the thio­phene-2,5-dicarboxyl­ate dianion bridges a pair of inversion-related dimethyl­acetamide-coordinated Zn(II) atoms, generating a layer motif parallel to (101). The Zn(II) atom shows a distorted square-pyramidal coordination; the apical site is occupied by the O atom of the dimethyl­acetamide mol­ecule, whereas the four basal sites are occupied by carboxyl­ate O atoms. In the crystal, the dimethyl­acetamide mol­ecule is disordered over two positions in a 0.72 (1):0.28 (1) ratio in respect of the C atoms. International Union of Crystallography 2011-10-05 /pmc/articles/PMC3246922/ /pubmed/22219742 http://dx.doi.org/10.1107/S160053681103981X Text en © Du and Ng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Du, Ming-Ming
Ng, Seik Weng
Poly[bis­(N,N-dimethyl­acetamide)-1κO,2κO-bis­(μ(4)-thio­phene-2,5-di­car­boxyl­ato-1:2:1′:2′κ(4) O (2):O (2′):O (5):O (5′))dizinc]
title Poly[bis­(N,N-dimethyl­acetamide)-1κO,2κO-bis­(μ(4)-thio­phene-2,5-di­car­boxyl­ato-1:2:1′:2′κ(4) O (2):O (2′):O (5):O (5′))dizinc]
title_full Poly[bis­(N,N-dimethyl­acetamide)-1κO,2κO-bis­(μ(4)-thio­phene-2,5-di­car­boxyl­ato-1:2:1′:2′κ(4) O (2):O (2′):O (5):O (5′))dizinc]
title_fullStr Poly[bis­(N,N-dimethyl­acetamide)-1κO,2κO-bis­(μ(4)-thio­phene-2,5-di­car­boxyl­ato-1:2:1′:2′κ(4) O (2):O (2′):O (5):O (5′))dizinc]
title_full_unstemmed Poly[bis­(N,N-dimethyl­acetamide)-1κO,2κO-bis­(μ(4)-thio­phene-2,5-di­car­boxyl­ato-1:2:1′:2′κ(4) O (2):O (2′):O (5):O (5′))dizinc]
title_short Poly[bis­(N,N-dimethyl­acetamide)-1κO,2κO-bis­(μ(4)-thio­phene-2,5-di­car­boxyl­ato-1:2:1′:2′κ(4) O (2):O (2′):O (5):O (5′))dizinc]
title_sort poly[bis­(n,n-dimethyl­acetamide)-1κo,2κo-bis­(μ(4)-thio­phene-2,5-di­car­boxyl­ato-1:2:1′:2′κ(4) o (2):o (2′):o (5):o (5′))dizinc]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246922/
https://www.ncbi.nlm.nih.gov/pubmed/22219742
http://dx.doi.org/10.1107/S160053681103981X
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