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Poly[bis(N,N-dimethylacetamide)-1κO,2κO-bis(μ(4)-thiophene-2,5-dicarboxylato-1:2:1′:2′κ(4) O (2):O (2′):O (5):O (5′))dizinc]
In the title polymeric complex, [Zn(2)(C(6)H(2)O(4)S)(2)(C(4)H(9)NO)(2)](n), each carboxylate group of the thiophene-2,5-dicarboxylate dianion bridges a pair of inversion-related dimethylacetamide-coordinated Zn(II) atoms, generating a layer motif parallel to (101). The Zn(II) atom shows a disto...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246922/ https://www.ncbi.nlm.nih.gov/pubmed/22219742 http://dx.doi.org/10.1107/S160053681103981X |
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author | Du, Ming-Ming Ng, Seik Weng |
author_facet | Du, Ming-Ming Ng, Seik Weng |
author_sort | Du, Ming-Ming |
collection | PubMed |
description | In the title polymeric complex, [Zn(2)(C(6)H(2)O(4)S)(2)(C(4)H(9)NO)(2)](n), each carboxylate group of the thiophene-2,5-dicarboxylate dianion bridges a pair of inversion-related dimethylacetamide-coordinated Zn(II) atoms, generating a layer motif parallel to (101). The Zn(II) atom shows a distorted square-pyramidal coordination; the apical site is occupied by the O atom of the dimethylacetamide molecule, whereas the four basal sites are occupied by carboxylate O atoms. In the crystal, the dimethylacetamide molecule is disordered over two positions in a 0.72 (1):0.28 (1) ratio in respect of the C atoms. |
format | Online Article Text |
id | pubmed-3246922 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32469222012-01-04 Poly[bis(N,N-dimethylacetamide)-1κO,2κO-bis(μ(4)-thiophene-2,5-dicarboxylato-1:2:1′:2′κ(4) O (2):O (2′):O (5):O (5′))dizinc] Du, Ming-Ming Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title polymeric complex, [Zn(2)(C(6)H(2)O(4)S)(2)(C(4)H(9)NO)(2)](n), each carboxylate group of the thiophene-2,5-dicarboxylate dianion bridges a pair of inversion-related dimethylacetamide-coordinated Zn(II) atoms, generating a layer motif parallel to (101). The Zn(II) atom shows a distorted square-pyramidal coordination; the apical site is occupied by the O atom of the dimethylacetamide molecule, whereas the four basal sites are occupied by carboxylate O atoms. In the crystal, the dimethylacetamide molecule is disordered over two positions in a 0.72 (1):0.28 (1) ratio in respect of the C atoms. International Union of Crystallography 2011-10-05 /pmc/articles/PMC3246922/ /pubmed/22219742 http://dx.doi.org/10.1107/S160053681103981X Text en © Du and Ng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Du, Ming-Ming Ng, Seik Weng Poly[bis(N,N-dimethylacetamide)-1κO,2κO-bis(μ(4)-thiophene-2,5-dicarboxylato-1:2:1′:2′κ(4) O (2):O (2′):O (5):O (5′))dizinc] |
title | Poly[bis(N,N-dimethylacetamide)-1κO,2κO-bis(μ(4)-thiophene-2,5-dicarboxylato-1:2:1′:2′κ(4)
O
(2):O
(2′):O
(5):O
(5′))dizinc] |
title_full | Poly[bis(N,N-dimethylacetamide)-1κO,2κO-bis(μ(4)-thiophene-2,5-dicarboxylato-1:2:1′:2′κ(4)
O
(2):O
(2′):O
(5):O
(5′))dizinc] |
title_fullStr | Poly[bis(N,N-dimethylacetamide)-1κO,2κO-bis(μ(4)-thiophene-2,5-dicarboxylato-1:2:1′:2′κ(4)
O
(2):O
(2′):O
(5):O
(5′))dizinc] |
title_full_unstemmed | Poly[bis(N,N-dimethylacetamide)-1κO,2κO-bis(μ(4)-thiophene-2,5-dicarboxylato-1:2:1′:2′κ(4)
O
(2):O
(2′):O
(5):O
(5′))dizinc] |
title_short | Poly[bis(N,N-dimethylacetamide)-1κO,2κO-bis(μ(4)-thiophene-2,5-dicarboxylato-1:2:1′:2′κ(4)
O
(2):O
(2′):O
(5):O
(5′))dizinc] |
title_sort | poly[bis(n,n-dimethylacetamide)-1κo,2κo-bis(μ(4)-thiophene-2,5-dicarboxylato-1:2:1′:2′κ(4)
o
(2):o
(2′):o
(5):o
(5′))dizinc] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246922/ https://www.ncbi.nlm.nih.gov/pubmed/22219742 http://dx.doi.org/10.1107/S160053681103981X |
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