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Aqua(4,4′-bipyridine-κN)bis(1,4-dioxo-1,4-dihydronaphthalen-2-olato-κ(2) O (1),O (2))zinc 4,4′-bipyridine monosolvate dihydrate
The reaction of 2-hydroxy-1,4-naphthoquinone and 4,4′-bipyridine with zinc acetate produced the title compound, [Zn(C(10)H(5)O(3))(2)(C(10)H(8)N(2))(H(2)O)]·C(10)H(8)N(2)·2H(2)O. The bond lengths and angles around the metal atom indicate a deviation from octahedral geometry. The two naphthoquino...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246923/ https://www.ncbi.nlm.nih.gov/pubmed/22219743 http://dx.doi.org/10.1107/S1600536811038682 |
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| author | Silva, Marcos M. P. Carvalho, Lucas J. Lanznaster, Maurício Resende, Jackson A. L. C. |
| author_facet | Silva, Marcos M. P. Carvalho, Lucas J. Lanznaster, Maurício Resende, Jackson A. L. C. |
| author_sort | Silva, Marcos M. P. |
| collection | PubMed |
| description | The reaction of 2-hydroxy-1,4-naphthoquinone and 4,4′-bipyridine with zinc acetate produced the title compound, [Zn(C(10)H(5)O(3))(2)(C(10)H(8)N(2))(H(2)O)]·C(10)H(8)N(2)·2H(2)O. The bond lengths and angles around the metal atom indicate a deviation from octahedral geometry. The two naphthoquinone ligands coordinate in a cis fashion, with the 4,4′-bipyridine ligand and the water molecules completing the coordination sphere of the metal atom. The asymmetric unit contains also one free 4,4′-bipyridine molecule and two uncoordinated water molecules. These molecules make contacts with the complex through O—H⋯N and O—H⋯O hydrogen bonds, creating a layer two-dimensional network parallel to (121). |
| format | Online Article Text |
| id | pubmed-3246923 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32469232012-01-04 Aqua(4,4′-bipyridine-κN)bis(1,4-dioxo-1,4-dihydronaphthalen-2-olato-κ(2) O (1),O (2))zinc 4,4′-bipyridine monosolvate dihydrate Silva, Marcos M. P. Carvalho, Lucas J. Lanznaster, Maurício Resende, Jackson A. L. C. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of 2-hydroxy-1,4-naphthoquinone and 4,4′-bipyridine with zinc acetate produced the title compound, [Zn(C(10)H(5)O(3))(2)(C(10)H(8)N(2))(H(2)O)]·C(10)H(8)N(2)·2H(2)O. The bond lengths and angles around the metal atom indicate a deviation from octahedral geometry. The two naphthoquinone ligands coordinate in a cis fashion, with the 4,4′-bipyridine ligand and the water molecules completing the coordination sphere of the metal atom. The asymmetric unit contains also one free 4,4′-bipyridine molecule and two uncoordinated water molecules. These molecules make contacts with the complex through O—H⋯N and O—H⋯O hydrogen bonds, creating a layer two-dimensional network parallel to (121). International Union of Crystallography 2011-10-05 /pmc/articles/PMC3246923/ /pubmed/22219743 http://dx.doi.org/10.1107/S1600536811038682 Text en © Silva et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Silva, Marcos M. P. Carvalho, Lucas J. Lanznaster, Maurício Resende, Jackson A. L. C. Aqua(4,4′-bipyridine-κN)bis(1,4-dioxo-1,4-dihydronaphthalen-2-olato-κ(2) O (1),O (2))zinc 4,4′-bipyridine monosolvate dihydrate |
| title | Aqua(4,4′-bipyridine-κN)bis(1,4-dioxo-1,4-dihydronaphthalen-2-olato-κ(2)
O
(1),O
(2))zinc 4,4′-bipyridine monosolvate dihydrate |
| title_full | Aqua(4,4′-bipyridine-κN)bis(1,4-dioxo-1,4-dihydronaphthalen-2-olato-κ(2)
O
(1),O
(2))zinc 4,4′-bipyridine monosolvate dihydrate |
| title_fullStr | Aqua(4,4′-bipyridine-κN)bis(1,4-dioxo-1,4-dihydronaphthalen-2-olato-κ(2)
O
(1),O
(2))zinc 4,4′-bipyridine monosolvate dihydrate |
| title_full_unstemmed | Aqua(4,4′-bipyridine-κN)bis(1,4-dioxo-1,4-dihydronaphthalen-2-olato-κ(2)
O
(1),O
(2))zinc 4,4′-bipyridine monosolvate dihydrate |
| title_short | Aqua(4,4′-bipyridine-κN)bis(1,4-dioxo-1,4-dihydronaphthalen-2-olato-κ(2)
O
(1),O
(2))zinc 4,4′-bipyridine monosolvate dihydrate |
| title_sort | aqua(4,4′-bipyridine-κn)bis(1,4-dioxo-1,4-dihydronaphthalen-2-olato-κ(2)
o
(1),o
(2))zinc 4,4′-bipyridine monosolvate dihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246923/ https://www.ncbi.nlm.nih.gov/pubmed/22219743 http://dx.doi.org/10.1107/S1600536811038682 |
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