Dibromidobis(3,5-dimethyl-1H-pyrazole-κN (2))cobalt(II)

In the mononuclear title complex, [CoBr(2)(C(5)H(8)N(2))(2)], the Co(II) atom is coordinated by two N atoms from two monodentate 3,5-dimethyl­pyrazole ligands and two Br atoms in a highly distorted tetra­hedral geometry. In the crystal, the complex mol­ecules are linked by inter­molecular N—H⋯Br hyd...

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Autores principales: Tomyn, Stefania, Pavlenko, Vadim A., Gumienna-Kontecka, Elżbieta, Penkova, Larysa, Kotova, Natalia V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246924/
https://www.ncbi.nlm.nih.gov/pubmed/22219744
http://dx.doi.org/10.1107/S1600536811039560
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author Tomyn, Stefania
Pavlenko, Vadim A.
Gumienna-Kontecka, Elżbieta
Penkova, Larysa
Kotova, Natalia V.
author_facet Tomyn, Stefania
Pavlenko, Vadim A.
Gumienna-Kontecka, Elżbieta
Penkova, Larysa
Kotova, Natalia V.
author_sort Tomyn, Stefania
collection PubMed
description In the mononuclear title complex, [CoBr(2)(C(5)H(8)N(2))(2)], the Co(II) atom is coordinated by two N atoms from two monodentate 3,5-dimethyl­pyrazole ligands and two Br atoms in a highly distorted tetra­hedral geometry. In the crystal, the complex mol­ecules are linked by inter­molecular N—H⋯Br hydrogen bonds into chains along [101]. An intra­molecular N—H⋯Br hydrogen bond is also present.
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spelling pubmed-32469242012-01-04 Dibromidobis(3,5-dimethyl-1H-pyrazole-κN (2))cobalt(II) Tomyn, Stefania Pavlenko, Vadim A. Gumienna-Kontecka, Elżbieta Penkova, Larysa Kotova, Natalia V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title complex, [CoBr(2)(C(5)H(8)N(2))(2)], the Co(II) atom is coordinated by two N atoms from two monodentate 3,5-dimethyl­pyrazole ligands and two Br atoms in a highly distorted tetra­hedral geometry. In the crystal, the complex mol­ecules are linked by inter­molecular N—H⋯Br hydrogen bonds into chains along [101]. An intra­molecular N—H⋯Br hydrogen bond is also present. International Union of Crystallography 2011-10-05 /pmc/articles/PMC3246924/ /pubmed/22219744 http://dx.doi.org/10.1107/S1600536811039560 Text en © Tomyn et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tomyn, Stefania
Pavlenko, Vadim A.
Gumienna-Kontecka, Elżbieta
Penkova, Larysa
Kotova, Natalia V.
Dibromidobis(3,5-dimethyl-1H-pyrazole-κN (2))cobalt(II)
title Dibromidobis(3,5-dimethyl-1H-pyrazole-κN (2))cobalt(II)
title_full Dibromidobis(3,5-dimethyl-1H-pyrazole-κN (2))cobalt(II)
title_fullStr Dibromidobis(3,5-dimethyl-1H-pyrazole-κN (2))cobalt(II)
title_full_unstemmed Dibromidobis(3,5-dimethyl-1H-pyrazole-κN (2))cobalt(II)
title_short Dibromidobis(3,5-dimethyl-1H-pyrazole-κN (2))cobalt(II)
title_sort dibromidobis(3,5-dimethyl-1h-pyrazole-κn (2))cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246924/
https://www.ncbi.nlm.nih.gov/pubmed/22219744
http://dx.doi.org/10.1107/S1600536811039560
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