Dichloridobis[3-meth­oxy­methyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]chromium(III) chloride

In the title complex, [CrCl(2)(C(15)H(14)N(4)O)(2)]Cl, the Cr(III) atom is located on a twofold rotation axis and is coordinated by two N,N′-bidentate triazole derivatives and two chloride ions in a distorted octa­hedral CrN(2)N′(2)Cl(2) geometry. One of the two independent Cl(−) counter-anions sits...

Descripción completa

Detalles Bibliográficos
Autores principales: Jin, Xiaofei, Wang, Zuoxiang, Cao, Shouping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246925/
https://www.ncbi.nlm.nih.gov/pubmed/22219745
http://dx.doi.org/10.1107/S1600536811039328
Descripción
Sumario:In the title complex, [CrCl(2)(C(15)H(14)N(4)O)(2)]Cl, the Cr(III) atom is located on a twofold rotation axis and is coordinated by two N,N′-bidentate triazole derivatives and two chloride ions in a distorted octa­hedral CrN(2)N′(2)Cl(2) geometry. One of the two independent Cl(−) counter-anions sits on a special position (site symmetry [Image: see text].) and is fully occupied, whereas the other is disordered around a twofold rotation axis over two positions in a 2:3 ratio.

Ejemplares similares