Dichloridobis[3-meth­oxy­methyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]chromium(III) chloride

In the title complex, [CrCl(2)(C(15)H(14)N(4)O)(2)]Cl, the Cr(III) atom is located on a twofold rotation axis and is coordinated by two N,N′-bidentate triazole derivatives and two chloride ions in a distorted octa­hedral CrN(2)N′(2)Cl(2) geometry. One of the two independent Cl(−) counter-anions sits...

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Detalles Bibliográficos
Autores principales: Jin, Xiaofei, Wang, Zuoxiang, Cao, Shouping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246925/
https://www.ncbi.nlm.nih.gov/pubmed/22219745
http://dx.doi.org/10.1107/S1600536811039328
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author Jin, Xiaofei
Wang, Zuoxiang
Cao, Shouping
author_facet Jin, Xiaofei
Wang, Zuoxiang
Cao, Shouping
author_sort Jin, Xiaofei
collection PubMed
description In the title complex, [CrCl(2)(C(15)H(14)N(4)O)(2)]Cl, the Cr(III) atom is located on a twofold rotation axis and is coordinated by two N,N′-bidentate triazole derivatives and two chloride ions in a distorted octa­hedral CrN(2)N′(2)Cl(2) geometry. One of the two independent Cl(−) counter-anions sits on a special position (site symmetry [Image: see text].) and is fully occupied, whereas the other is disordered around a twofold rotation axis over two positions in a 2:3 ratio.
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spelling pubmed-32469252012-01-04 Dichloridobis[3-meth­oxy­methyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]chromium(III) chloride Jin, Xiaofei Wang, Zuoxiang Cao, Shouping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CrCl(2)(C(15)H(14)N(4)O)(2)]Cl, the Cr(III) atom is located on a twofold rotation axis and is coordinated by two N,N′-bidentate triazole derivatives and two chloride ions in a distorted octa­hedral CrN(2)N′(2)Cl(2) geometry. One of the two independent Cl(−) counter-anions sits on a special position (site symmetry [Image: see text].) and is fully occupied, whereas the other is disordered around a twofold rotation axis over two positions in a 2:3 ratio. International Union of Crystallography 2011-10-05 /pmc/articles/PMC3246925/ /pubmed/22219745 http://dx.doi.org/10.1107/S1600536811039328 Text en © Jin et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jin, Xiaofei
Wang, Zuoxiang
Cao, Shouping
Dichloridobis[3-meth­oxy­methyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]chromium(III) chloride
title Dichloridobis[3-meth­oxy­methyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]chromium(III) chloride
title_full Dichloridobis[3-meth­oxy­methyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]chromium(III) chloride
title_fullStr Dichloridobis[3-meth­oxy­methyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]chromium(III) chloride
title_full_unstemmed Dichloridobis[3-meth­oxy­methyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]chromium(III) chloride
title_short Dichloridobis[3-meth­oxy­methyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]chromium(III) chloride
title_sort dichloridobis[3-meth­oxy­methyl-4-phenyl-5-(2-pyrid­yl)-4h-1,2,4-triazole-κ(2) n (1),n (5)]chromium(iii) chloride
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246925/
https://www.ncbi.nlm.nih.gov/pubmed/22219745
http://dx.doi.org/10.1107/S1600536811039328
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AT caoshouping dichloridobis3methoxymethyl4phenyl52pyridyl4h124triazolek2n1n5chromiumiiichloride

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