(Methano­lato-κO)[N′-(3-meth­oxy-2-oxidobenzyl­idene-κO (2))-4-nitro­benzo­hydrazidato-κ(2) N′,O]oxidovanadium(V)

The title oxidovanadium(V) complex, [V(C(15)H(11)N(3)O(5))(CH(3)O)O], was obtained by the reaction of 2-hy­droxy-3-meth­oxy­benzaldehyde, 4-nitro­benzohydrazide and vanadyl sulfate in methanol. The V(V) atom is five-coordinated by the two O and one N donor atoms of the Schiff base ligand, one methan...

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Detalles Bibliográficos
Autores principales: Wang, Chen-Yi, Tu, Hai-Yu, Zhu, Pei-Fei, Sheng, Su-Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246927/
https://www.ncbi.nlm.nih.gov/pubmed/22219747
http://dx.doi.org/10.1107/S1600536811040207
Descripción
Sumario:The title oxidovanadium(V) complex, [V(C(15)H(11)N(3)O(5))(CH(3)O)O], was obtained by the reaction of 2-hy­droxy-3-meth­oxy­benzaldehyde, 4-nitro­benzohydrazide and vanadyl sulfate in methanol. The V(V) atom is five-coordinated by the two O and one N donor atoms of the Schiff base ligand, one methano­late O atom and one oxido O atom, forming a distorted square-pyramidal geometry.

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