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(Methanolato-κO)[N′-(3-methoxy-2-oxidobenzylidene-κO (2))-4-nitrobenzohydrazidato-κ(2) N′,O]oxidovanadium(V)
The title oxidovanadium(V) complex, [V(C(15)H(11)N(3)O(5))(CH(3)O)O], was obtained by the reaction of 2-hydroxy-3-methoxybenzaldehyde, 4-nitrobenzohydrazide and vanadyl sulfate in methanol. The V(V) atom is five-coordinated by the two O and one N donor atoms of the Schiff base ligand, one methan...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246927/ https://www.ncbi.nlm.nih.gov/pubmed/22219747 http://dx.doi.org/10.1107/S1600536811040207 |
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author | Wang, Chen-Yi Tu, Hai-Yu Zhu, Pei-Fei Sheng, Su-Jun |
author_facet | Wang, Chen-Yi Tu, Hai-Yu Zhu, Pei-Fei Sheng, Su-Jun |
author_sort | Wang, Chen-Yi |
collection | PubMed |
description | The title oxidovanadium(V) complex, [V(C(15)H(11)N(3)O(5))(CH(3)O)O], was obtained by the reaction of 2-hydroxy-3-methoxybenzaldehyde, 4-nitrobenzohydrazide and vanadyl sulfate in methanol. The V(V) atom is five-coordinated by the two O and one N donor atoms of the Schiff base ligand, one methanolate O atom and one oxido O atom, forming a distorted square-pyramidal geometry. |
format | Online Article Text |
id | pubmed-3246927 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32469272012-01-04 (Methanolato-κO)[N′-(3-methoxy-2-oxidobenzylidene-κO (2))-4-nitrobenzohydrazidato-κ(2) N′,O]oxidovanadium(V) Wang, Chen-Yi Tu, Hai-Yu Zhu, Pei-Fei Sheng, Su-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title oxidovanadium(V) complex, [V(C(15)H(11)N(3)O(5))(CH(3)O)O], was obtained by the reaction of 2-hydroxy-3-methoxybenzaldehyde, 4-nitrobenzohydrazide and vanadyl sulfate in methanol. The V(V) atom is five-coordinated by the two O and one N donor atoms of the Schiff base ligand, one methanolate O atom and one oxido O atom, forming a distorted square-pyramidal geometry. International Union of Crystallography 2011-10-05 /pmc/articles/PMC3246927/ /pubmed/22219747 http://dx.doi.org/10.1107/S1600536811040207 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Chen-Yi Tu, Hai-Yu Zhu, Pei-Fei Sheng, Su-Jun (Methanolato-κO)[N′-(3-methoxy-2-oxidobenzylidene-κO (2))-4-nitrobenzohydrazidato-κ(2) N′,O]oxidovanadium(V) |
title | (Methanolato-κO)[N′-(3-methoxy-2-oxidobenzylidene-κO
(2))-4-nitrobenzohydrazidato-κ(2)
N′,O]oxidovanadium(V) |
title_full | (Methanolato-κO)[N′-(3-methoxy-2-oxidobenzylidene-κO
(2))-4-nitrobenzohydrazidato-κ(2)
N′,O]oxidovanadium(V) |
title_fullStr | (Methanolato-κO)[N′-(3-methoxy-2-oxidobenzylidene-κO
(2))-4-nitrobenzohydrazidato-κ(2)
N′,O]oxidovanadium(V) |
title_full_unstemmed | (Methanolato-κO)[N′-(3-methoxy-2-oxidobenzylidene-κO
(2))-4-nitrobenzohydrazidato-κ(2)
N′,O]oxidovanadium(V) |
title_short | (Methanolato-κO)[N′-(3-methoxy-2-oxidobenzylidene-κO
(2))-4-nitrobenzohydrazidato-κ(2)
N′,O]oxidovanadium(V) |
title_sort | (methanolato-κo)[n′-(3-methoxy-2-oxidobenzylidene-κo
(2))-4-nitrobenzohydrazidato-κ(2)
n′,o]oxidovanadium(v) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246927/ https://www.ncbi.nlm.nih.gov/pubmed/22219747 http://dx.doi.org/10.1107/S1600536811040207 |
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