Dichlorido{N-[2-(diphenylphosphanyl)benzylidene]-2,6-diisopropylaniline-κ(2) P,N}platinum(II)

The title compound, [PtCl(2)(C(31)H(32)NP)], is a Pt(II) complex with an NPCl(2) coordination sphere in which the Pt(II) atom is coordinated to the imino N and phosphane P atoms of the ligand and to two cis Cl ions, giving a slightly distorted square-planar geometry. The P—Pt—N angle is 89.80 (5)° a...

Descripción completa

Detalles Bibliográficos
Autores principales: Chiririwa, Haleden, Meijboom, Reinout
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246928/
https://www.ncbi.nlm.nih.gov/pubmed/22219748
http://dx.doi.org/10.1107/S1600536811040098
Descripción
Sumario:The title compound, [PtCl(2)(C(31)H(32)NP)], is a Pt(II) complex with an NPCl(2) coordination sphere in which the Pt(II) atom is coordinated to the imino N and phosphane P atoms of the ligand and to two cis Cl ions, giving a slightly distorted square-planar geometry. The P—Pt—N angle is 89.80 (5)° and the corresponding angle between the Cl ions is 87.92 (2)°.

Ejemplares similares