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Dichlorido[2-diphenyl­phosphanyl-N-(pyridin-3-ylmeth­yl)benzyl­idenamine-κ(2) P,N]platinum(II)

The title compound, [PtCl(2)(C(25)H(21)N(2)P)], is a Pt(II) complex with an NPCl(2) coordination sphere in which the metal is coordinated to the imino N and phosphane P atoms of the ligand and to two chloride ions. The Pt(II) atom is in a distorted square-planar environment and is bound to the ligan...

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Detalles Bibliográficos
Autores principales: Chiririwa, Haleden, Meijboom, Reinout
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246929/
https://www.ncbi.nlm.nih.gov/pubmed/22219749
http://dx.doi.org/10.1107/S1600536811040086
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author Chiririwa, Haleden
Meijboom, Reinout
author_facet Chiririwa, Haleden
Meijboom, Reinout
author_sort Chiririwa, Haleden
collection PubMed
description The title compound, [PtCl(2)(C(25)H(21)N(2)P)], is a Pt(II) complex with an NPCl(2) coordination sphere in which the metal is coordinated to the imino N and phosphane P atoms of the ligand and to two chloride ions. The Pt(II) atom is in a distorted square-planar environment and is bound to the ligand via the P and amine N atoms in a cis fashion, with the chlorine atoms located at the two remaining sites.
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spelling pubmed-32469292012-01-04 Dichlorido[2-diphenyl­phosphanyl-N-(pyridin-3-ylmeth­yl)benzyl­idenamine-κ(2) P,N]platinum(II) Chiririwa, Haleden Meijboom, Reinout Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [PtCl(2)(C(25)H(21)N(2)P)], is a Pt(II) complex with an NPCl(2) coordination sphere in which the metal is coordinated to the imino N and phosphane P atoms of the ligand and to two chloride ions. The Pt(II) atom is in a distorted square-planar environment and is bound to the ligand via the P and amine N atoms in a cis fashion, with the chlorine atoms located at the two remaining sites. International Union of Crystallography 2011-10-05 /pmc/articles/PMC3246929/ /pubmed/22219749 http://dx.doi.org/10.1107/S1600536811040086 Text en © Chiririwa and Meijboom 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chiririwa, Haleden
Meijboom, Reinout
Dichlorido[2-diphenyl­phosphanyl-N-(pyridin-3-ylmeth­yl)benzyl­idenamine-κ(2) P,N]platinum(II)
title Dichlorido[2-diphenyl­phosphanyl-N-(pyridin-3-ylmeth­yl)benzyl­idenamine-κ(2) P,N]platinum(II)
title_full Dichlorido[2-diphenyl­phosphanyl-N-(pyridin-3-ylmeth­yl)benzyl­idenamine-κ(2) P,N]platinum(II)
title_fullStr Dichlorido[2-diphenyl­phosphanyl-N-(pyridin-3-ylmeth­yl)benzyl­idenamine-κ(2) P,N]platinum(II)
title_full_unstemmed Dichlorido[2-diphenyl­phosphanyl-N-(pyridin-3-ylmeth­yl)benzyl­idenamine-κ(2) P,N]platinum(II)
title_short Dichlorido[2-diphenyl­phosphanyl-N-(pyridin-3-ylmeth­yl)benzyl­idenamine-κ(2) P,N]platinum(II)
title_sort dichlorido[2-diphenyl­phosphanyl-n-(pyridin-3-ylmeth­yl)benzyl­idenamine-κ(2) p,n]platinum(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246929/
https://www.ncbi.nlm.nih.gov/pubmed/22219749
http://dx.doi.org/10.1107/S1600536811040086
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