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(SP-4-2)-Chlorido{N-[2-(diphenyl­phosphan­yl)benzyl­idene]benzyl­amine-κ(2) P,N}(meth­yl)palladium(II)

In the title Pd(II) complex, [Pd(CH(3))Cl(C(26)H(22)NP)], the Pd(II) atom is coordinated in a slightly distorted square-planar geometry by the imino N and phosphane P atoms of the ligand, by one chloride ion and by a methyl ligand. The methyl group is trans to the N atom of the ligand.

Detalles Bibliográficos
Autores principales: Chiririwa, Haleden, Meijboom, Reinout
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246930/
https://www.ncbi.nlm.nih.gov/pubmed/22219750
http://dx.doi.org/10.1107/S1600536811040074
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author Chiririwa, Haleden
Meijboom, Reinout
author_facet Chiririwa, Haleden
Meijboom, Reinout
author_sort Chiririwa, Haleden
collection PubMed
description In the title Pd(II) complex, [Pd(CH(3))Cl(C(26)H(22)NP)], the Pd(II) atom is coordinated in a slightly distorted square-planar geometry by the imino N and phosphane P atoms of the ligand, by one chloride ion and by a methyl ligand. The methyl group is trans to the N atom of the ligand.
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spelling pubmed-32469302012-01-04 (SP-4-2)-Chlorido{N-[2-(diphenyl­phosphan­yl)benzyl­idene]benzyl­amine-κ(2) P,N}(meth­yl)palladium(II) Chiririwa, Haleden Meijboom, Reinout Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title Pd(II) complex, [Pd(CH(3))Cl(C(26)H(22)NP)], the Pd(II) atom is coordinated in a slightly distorted square-planar geometry by the imino N and phosphane P atoms of the ligand, by one chloride ion and by a methyl ligand. The methyl group is trans to the N atom of the ligand. International Union of Crystallography 2011-10-05 /pmc/articles/PMC3246930/ /pubmed/22219750 http://dx.doi.org/10.1107/S1600536811040074 Text en © Chiririwa and Meijboom 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chiririwa, Haleden
Meijboom, Reinout
(SP-4-2)-Chlorido{N-[2-(diphenyl­phosphan­yl)benzyl­idene]benzyl­amine-κ(2) P,N}(meth­yl)palladium(II)
title (SP-4-2)-Chlorido{N-[2-(diphenyl­phosphan­yl)benzyl­idene]benzyl­amine-κ(2) P,N}(meth­yl)palladium(II)
title_full (SP-4-2)-Chlorido{N-[2-(diphenyl­phosphan­yl)benzyl­idene]benzyl­amine-κ(2) P,N}(meth­yl)palladium(II)
title_fullStr (SP-4-2)-Chlorido{N-[2-(diphenyl­phosphan­yl)benzyl­idene]benzyl­amine-κ(2) P,N}(meth­yl)palladium(II)
title_full_unstemmed (SP-4-2)-Chlorido{N-[2-(diphenyl­phosphan­yl)benzyl­idene]benzyl­amine-κ(2) P,N}(meth­yl)palladium(II)
title_short (SP-4-2)-Chlorido{N-[2-(diphenyl­phosphan­yl)benzyl­idene]benzyl­amine-κ(2) P,N}(meth­yl)palladium(II)
title_sort (sp-4-2)-chlorido{n-[2-(diphenyl­phosphan­yl)benzyl­idene]benzyl­amine-κ(2) p,n}(meth­yl)palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246930/
https://www.ncbi.nlm.nih.gov/pubmed/22219750
http://dx.doi.org/10.1107/S1600536811040074
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