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[1,2-Bis(diphenylphosphanyl)ethane-2κ(2) P,P′]tetracarbonyl-1κ(3) C,2κC-(μ-2-cyclopentyl-2-azapropane-1,3-dithiolato-1:2κ(4) S,S′:S,S′)diiron(II)(Fe—Fe)
In the title compound, [Fe(2)(C(7)H(13)NS(2))(C(26)H(24)P(2))(CO)(4)], the Fe(2)S(2) core exhibits a butterfly-like shape, with two S atoms bridging the Fe–Fe dumbbell. Each of the two Fe atoms exhibits a distorted octahedral environment. One Fe atom is additionally bonded to three carbonyl C atoms...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246932/ https://www.ncbi.nlm.nih.gov/pubmed/22219752 http://dx.doi.org/10.1107/S1600536811040347 |
Sumario: | In the title compound, [Fe(2)(C(7)H(13)NS(2))(C(26)H(24)P(2))(CO)(4)], the Fe(2)S(2) core exhibits a butterfly-like shape, with two S atoms bridging the Fe–Fe dumbbell. Each of the two Fe atoms exhibits a distorted octahedral environment. One Fe atom is additionally bonded to three carbonyl C atoms, whereas the other Fe atom is additionally bonded to one carbonyl C atom and two P atoms of the chelating dppe [dppe = 1,2-bis(diphenylphosphanyl)ethane] ligand. Non-classical intramolecular C—H⋯S hydrogen-bonding interactions are present in the structure. The packing of adjacent molecules along [100] is accomplished mainly through van der Waals forces. |
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