[1,2-Bis(diphenyl­phosphan­yl)ethane-2κ(2) P,P′]tetra­carbonyl-1κ(3) C,2κC-(μ-2-cyclo­pentyl-2-aza­propane-1,3-dithiol­ato-1:2κ(4) S,S′:S,S′)diiron(II)(Fe—Fe)

In the title compound, [Fe(2)(C(7)H(13)NS(2))(C(26)H(24)P(2))(CO)(4)], the Fe(2)S(2) core exhibits a butterfly-like shape, with two S atoms bridging the Fe–Fe dumbbell. Each of the two Fe atoms exhibits a distorted octa­hedral environment. One Fe atom is additionally bonded to three carbonyl C atoms...

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Detalles Bibliográficos
Autores principales: Si, Youtao, Chen, Hui, Chen, ChangNeng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246932/
https://www.ncbi.nlm.nih.gov/pubmed/22219752
http://dx.doi.org/10.1107/S1600536811040347
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author Si, Youtao
Chen, Hui
Chen, ChangNeng
author_facet Si, Youtao
Chen, Hui
Chen, ChangNeng
author_sort Si, Youtao
collection PubMed
description In the title compound, [Fe(2)(C(7)H(13)NS(2))(C(26)H(24)P(2))(CO)(4)], the Fe(2)S(2) core exhibits a butterfly-like shape, with two S atoms bridging the Fe–Fe dumbbell. Each of the two Fe atoms exhibits a distorted octa­hedral environment. One Fe atom is additionally bonded to three carbonyl C atoms, whereas the other Fe atom is additionally bonded to one carbonyl C atom and two P atoms of the chelating dppe [dppe = 1,2-bis­(diphenyl­phosphan­yl)ethane] ligand. Non-classical intra­molecular C—H⋯S hydrogen-bonding inter­actions are present in the structure. The packing of adjacent mol­ecules along [100] is accomplished mainly through van der Waals forces.
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spelling pubmed-32469322012-01-04 [1,2-Bis(diphenyl­phosphan­yl)ethane-2κ(2) P,P′]tetra­carbonyl-1κ(3) C,2κC-(μ-2-cyclo­pentyl-2-aza­propane-1,3-dithiol­ato-1:2κ(4) S,S′:S,S′)diiron(II)(Fe—Fe) Si, Youtao Chen, Hui Chen, ChangNeng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(2)(C(7)H(13)NS(2))(C(26)H(24)P(2))(CO)(4)], the Fe(2)S(2) core exhibits a butterfly-like shape, with two S atoms bridging the Fe–Fe dumbbell. Each of the two Fe atoms exhibits a distorted octa­hedral environment. One Fe atom is additionally bonded to three carbonyl C atoms, whereas the other Fe atom is additionally bonded to one carbonyl C atom and two P atoms of the chelating dppe [dppe = 1,2-bis­(diphenyl­phosphan­yl)ethane] ligand. Non-classical intra­molecular C—H⋯S hydrogen-bonding inter­actions are present in the structure. The packing of adjacent mol­ecules along [100] is accomplished mainly through van der Waals forces. International Union of Crystallography 2011-10-08 /pmc/articles/PMC3246932/ /pubmed/22219752 http://dx.doi.org/10.1107/S1600536811040347 Text en © Si et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Si, Youtao
Chen, Hui
Chen, ChangNeng
[1,2-Bis(diphenyl­phosphan­yl)ethane-2κ(2) P,P′]tetra­carbonyl-1κ(3) C,2κC-(μ-2-cyclo­pentyl-2-aza­propane-1,3-dithiol­ato-1:2κ(4) S,S′:S,S′)diiron(II)(Fe—Fe)
title [1,2-Bis(diphenyl­phosphan­yl)ethane-2κ(2) P,P′]tetra­carbonyl-1κ(3) C,2κC-(μ-2-cyclo­pentyl-2-aza­propane-1,3-dithiol­ato-1:2κ(4) S,S′:S,S′)diiron(II)(Fe—Fe)
title_full [1,2-Bis(diphenyl­phosphan­yl)ethane-2κ(2) P,P′]tetra­carbonyl-1κ(3) C,2κC-(μ-2-cyclo­pentyl-2-aza­propane-1,3-dithiol­ato-1:2κ(4) S,S′:S,S′)diiron(II)(Fe—Fe)
title_fullStr [1,2-Bis(diphenyl­phosphan­yl)ethane-2κ(2) P,P′]tetra­carbonyl-1κ(3) C,2κC-(μ-2-cyclo­pentyl-2-aza­propane-1,3-dithiol­ato-1:2κ(4) S,S′:S,S′)diiron(II)(Fe—Fe)
title_full_unstemmed [1,2-Bis(diphenyl­phosphan­yl)ethane-2κ(2) P,P′]tetra­carbonyl-1κ(3) C,2κC-(μ-2-cyclo­pentyl-2-aza­propane-1,3-dithiol­ato-1:2κ(4) S,S′:S,S′)diiron(II)(Fe—Fe)
title_short [1,2-Bis(diphenyl­phosphan­yl)ethane-2κ(2) P,P′]tetra­carbonyl-1κ(3) C,2κC-(μ-2-cyclo­pentyl-2-aza­propane-1,3-dithiol­ato-1:2κ(4) S,S′:S,S′)diiron(II)(Fe—Fe)
title_sort [1,2-bis(diphenyl­phosphan­yl)ethane-2κ(2) p,p′]tetra­carbonyl-1κ(3) c,2κc-(μ-2-cyclo­pentyl-2-aza­propane-1,3-dithiol­ato-1:2κ(4) s,s′:s,s′)diiron(ii)(fe—fe)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246932/
https://www.ncbi.nlm.nih.gov/pubmed/22219752
http://dx.doi.org/10.1107/S1600536811040347
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