Dichloridobis[4,4,5,5-tetra­methyl-2-(5-methyl-1H-imidazol-4-yl-κN (3))-2-imidazoline-1-oxyl 3-oxide-κO]copper(II)

In the title complex, [CuCl(2)(C(11)H(17)N(4)O(2))(2)], the Cu(II) ion, lying on an inversion center, is six-coordinated in a distorted octa­hedral [Cu(N(2)O(2)Cl(2))] environment by two N,O-bidentate nitronyl nitroxide radical ligands and two trans-chloride anions. In the imidazoline-1-oxyl-3-oxide...

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Detalles Bibliográficos
Autores principales: Gao, Zhi Yong, Zhang, Wen Bei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246935/
https://www.ncbi.nlm.nih.gov/pubmed/22219755
http://dx.doi.org/10.1107/S1600536811040475
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author Gao, Zhi Yong
Zhang, Wen Bei
author_facet Gao, Zhi Yong
Zhang, Wen Bei
author_sort Gao, Zhi Yong
collection PubMed
description In the title complex, [CuCl(2)(C(11)H(17)N(4)O(2))(2)], the Cu(II) ion, lying on an inversion center, is six-coordinated in a distorted octa­hedral [Cu(N(2)O(2)Cl(2))] environment by two N,O-bidentate nitronyl nitroxide radical ligands and two trans-chloride anions. In the imidazoline-1-oxyl-3-oxide unit of the ligand, the four methyl groups and the C atoms to which they are bonded are disordered over two sets of sites, with a refined occupancy ratio of 0.737 (5):0.263 (5).
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spelling pubmed-32469352012-01-04 Dichloridobis[4,4,5,5-tetra­methyl-2-(5-methyl-1H-imidazol-4-yl-κN (3))-2-imidazoline-1-oxyl 3-oxide-κO]copper(II) Gao, Zhi Yong Zhang, Wen Bei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CuCl(2)(C(11)H(17)N(4)O(2))(2)], the Cu(II) ion, lying on an inversion center, is six-coordinated in a distorted octa­hedral [Cu(N(2)O(2)Cl(2))] environment by two N,O-bidentate nitronyl nitroxide radical ligands and two trans-chloride anions. In the imidazoline-1-oxyl-3-oxide unit of the ligand, the four methyl groups and the C atoms to which they are bonded are disordered over two sets of sites, with a refined occupancy ratio of 0.737 (5):0.263 (5). International Union of Crystallography 2011-10-08 /pmc/articles/PMC3246935/ /pubmed/22219755 http://dx.doi.org/10.1107/S1600536811040475 Text en © Gao and Zhang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Zhi Yong
Zhang, Wen Bei
Dichloridobis[4,4,5,5-tetra­methyl-2-(5-methyl-1H-imidazol-4-yl-κN (3))-2-imidazoline-1-oxyl 3-oxide-κO]copper(II)
title Dichloridobis[4,4,5,5-tetra­methyl-2-(5-methyl-1H-imidazol-4-yl-κN (3))-2-imidazoline-1-oxyl 3-oxide-κO]copper(II)
title_full Dichloridobis[4,4,5,5-tetra­methyl-2-(5-methyl-1H-imidazol-4-yl-κN (3))-2-imidazoline-1-oxyl 3-oxide-κO]copper(II)
title_fullStr Dichloridobis[4,4,5,5-tetra­methyl-2-(5-methyl-1H-imidazol-4-yl-κN (3))-2-imidazoline-1-oxyl 3-oxide-κO]copper(II)
title_full_unstemmed Dichloridobis[4,4,5,5-tetra­methyl-2-(5-methyl-1H-imidazol-4-yl-κN (3))-2-imidazoline-1-oxyl 3-oxide-κO]copper(II)
title_short Dichloridobis[4,4,5,5-tetra­methyl-2-(5-methyl-1H-imidazol-4-yl-κN (3))-2-imidazoline-1-oxyl 3-oxide-κO]copper(II)
title_sort dichloridobis[4,4,5,5-tetra­methyl-2-(5-methyl-1h-imidazol-4-yl-κn (3))-2-imidazoline-1-oxyl 3-oxide-κo]copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246935/
https://www.ncbi.nlm.nih.gov/pubmed/22219755
http://dx.doi.org/10.1107/S1600536811040475
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AT zhangwenbei dichloridobis4455tetramethyl25methyl1himidazol4ylkn32imidazoline1oxyl3oxidekocopperii

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