catena-Poly[[tris[silver(I)-μ-4,4′-bi­pyridine-κ(2) N:N′]] tris­(perchlorate) di­hydrate]

In the title compound, {[Ag(3)(C(10)H(8)N(2))(3)](ClO(4))(3)·2H(2)O}(n), one of the Ag(I) ions, one of the 4,4′-bipyridine (bipy) ligands and one of the perchlorate anions are each situated on a twofold rotation axis. Each Ag(I) ion is coordinated by two N atoms from two bridging bipy ligands, formi...

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Detalles Bibliográficos
Autores principales: Hu, Xiao-Ming, Li, Fu-An
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246936/
https://www.ncbi.nlm.nih.gov/pubmed/22219756
http://dx.doi.org/10.1107/S1600536811040153
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author Hu, Xiao-Ming
Li, Fu-An
author_facet Hu, Xiao-Ming
Li, Fu-An
author_sort Hu, Xiao-Ming
collection PubMed
description In the title compound, {[Ag(3)(C(10)H(8)N(2))(3)](ClO(4))(3)·2H(2)O}(n), one of the Ag(I) ions, one of the 4,4′-bipyridine (bipy) ligands and one of the perchlorate anions are each situated on a twofold rotation axis. Each Ag(I) ion is coordinated by two N atoms from two bridging bipy ligands, forming chains along [101]. π–π inter­actions between the pyridine rings [centroid–centroid distances = 3.638 (8) and 3.688 (8) Å] connect the chains. Inter­molecular O—H⋯O hydrogen bonds link the uncoord­inated water mol­ecules and the perchlorate anions.
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spelling pubmed-32469362012-01-04 catena-Poly[[tris[silver(I)-μ-4,4′-bi­pyridine-κ(2) N:N′]] tris­(perchlorate) di­hydrate] Hu, Xiao-Ming Li, Fu-An Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Ag(3)(C(10)H(8)N(2))(3)](ClO(4))(3)·2H(2)O}(n), one of the Ag(I) ions, one of the 4,4′-bipyridine (bipy) ligands and one of the perchlorate anions are each situated on a twofold rotation axis. Each Ag(I) ion is coordinated by two N atoms from two bridging bipy ligands, forming chains along [101]. π–π inter­actions between the pyridine rings [centroid–centroid distances = 3.638 (8) and 3.688 (8) Å] connect the chains. Inter­molecular O—H⋯O hydrogen bonds link the uncoord­inated water mol­ecules and the perchlorate anions. International Union of Crystallography 2011-10-08 /pmc/articles/PMC3246936/ /pubmed/22219756 http://dx.doi.org/10.1107/S1600536811040153 Text en © Hu and Li 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hu, Xiao-Ming
Li, Fu-An
catena-Poly[[tris[silver(I)-μ-4,4′-bi­pyridine-κ(2) N:N′]] tris­(perchlorate) di­hydrate]
title catena-Poly[[tris[silver(I)-μ-4,4′-bi­pyridine-κ(2) N:N′]] tris­(perchlorate) di­hydrate]
title_full catena-Poly[[tris[silver(I)-μ-4,4′-bi­pyridine-κ(2) N:N′]] tris­(perchlorate) di­hydrate]
title_fullStr catena-Poly[[tris[silver(I)-μ-4,4′-bi­pyridine-κ(2) N:N′]] tris­(perchlorate) di­hydrate]
title_full_unstemmed catena-Poly[[tris[silver(I)-μ-4,4′-bi­pyridine-κ(2) N:N′]] tris­(perchlorate) di­hydrate]
title_short catena-Poly[[tris[silver(I)-μ-4,4′-bi­pyridine-κ(2) N:N′]] tris­(perchlorate) di­hydrate]
title_sort catena-poly[[tris[silver(i)-μ-4,4′-bi­pyridine-κ(2) n:n′]] tris­(perchlorate) di­hydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246936/
https://www.ncbi.nlm.nih.gov/pubmed/22219756
http://dx.doi.org/10.1107/S1600536811040153
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AT lifuan catenapolytrissilverim44bipyridinek2nntrisperchloratedihydrate

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