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Bromidotris(triphenylphosphane)silver acetonitrile monosolvate monohydrate
In the title compound, [AgBr(C(18)H(15)P)(3)]·C(2)H(3)N·H(2)O, the coordination of the Ag atom is close to ideal tetrahedral, with the three Ag—P bond lengths almost equal [2.5441 (10), 2.5523 (9) and 2.5647 (10) ° A] and the Ag—Br bond slightly longer [2.7242 (5) Å]. The coordination tetrahedron...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246938/ https://www.ncbi.nlm.nih.gov/pubmed/22219758 http://dx.doi.org/10.1107/S1600536811040827 |
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author | Owczarzak, Anita M. Kyros, Loukas Hadjikakou, Sotiris K. Kubicki, Maciej |
author_facet | Owczarzak, Anita M. Kyros, Loukas Hadjikakou, Sotiris K. Kubicki, Maciej |
author_sort | Owczarzak, Anita M. |
collection | PubMed |
description | In the title compound, [AgBr(C(18)H(15)P)(3)]·C(2)H(3)N·H(2)O, the coordination of the Ag atom is close to ideal tetrahedral, with the three Ag—P bond lengths almost equal [2.5441 (10), 2.5523 (9) and 2.5647 (10) ° A] and the Ag—Br bond slightly longer [2.7242 (5) Å]. The coordination tetrahedron is slightly flattened, the Ag atom is closer to the PPP plane; the P—Ag—P angles are wider than the Br—Ag—P angles. The voids in the crystal structure are filled with ordered acetonitrile solvent molecules. The remaining electron density was interpreted as a water molecule, disordered over three alternative positions. Neither of the solvent molecules is connected by any directional specific interactions with the complex. |
format | Online Article Text |
id | pubmed-3246938 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32469382012-01-04 Bromidotris(triphenylphosphane)silver acetonitrile monosolvate monohydrate Owczarzak, Anita M. Kyros, Loukas Hadjikakou, Sotiris K. Kubicki, Maciej Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [AgBr(C(18)H(15)P)(3)]·C(2)H(3)N·H(2)O, the coordination of the Ag atom is close to ideal tetrahedral, with the three Ag—P bond lengths almost equal [2.5441 (10), 2.5523 (9) and 2.5647 (10) ° A] and the Ag—Br bond slightly longer [2.7242 (5) Å]. The coordination tetrahedron is slightly flattened, the Ag atom is closer to the PPP plane; the P—Ag—P angles are wider than the Br—Ag—P angles. The voids in the crystal structure are filled with ordered acetonitrile solvent molecules. The remaining electron density was interpreted as a water molecule, disordered over three alternative positions. Neither of the solvent molecules is connected by any directional specific interactions with the complex. International Union of Crystallography 2011-10-08 /pmc/articles/PMC3246938/ /pubmed/22219758 http://dx.doi.org/10.1107/S1600536811040827 Text en © Owczarzak et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Owczarzak, Anita M. Kyros, Loukas Hadjikakou, Sotiris K. Kubicki, Maciej Bromidotris(triphenylphosphane)silver acetonitrile monosolvate monohydrate |
title | Bromidotris(triphenylphosphane)silver acetonitrile monosolvate monohydrate |
title_full | Bromidotris(triphenylphosphane)silver acetonitrile monosolvate monohydrate |
title_fullStr | Bromidotris(triphenylphosphane)silver acetonitrile monosolvate monohydrate |
title_full_unstemmed | Bromidotris(triphenylphosphane)silver acetonitrile monosolvate monohydrate |
title_short | Bromidotris(triphenylphosphane)silver acetonitrile monosolvate monohydrate |
title_sort | bromidotris(triphenylphosphane)silver acetonitrile monosolvate monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246938/ https://www.ncbi.nlm.nih.gov/pubmed/22219758 http://dx.doi.org/10.1107/S1600536811040827 |
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