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Bromidotris(triphenyl­phosphane)silver acetonitrile monosolvate monohydrate

In the title compound, [AgBr(C(18)H(15)P)(3)]·C(2)H(3)N·H(2)O, the coordination of the Ag atom is close to ideal tetra­hedral, with the three Ag—P bond lengths almost equal [2.5441 (10), 2.5523 (9) and 2.5647 (10) ° A] and the Ag—Br bond slightly longer [2.7242 (5) Å]. The coordination tetra­hedron...

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Autores principales: Owczarzak, Anita M., Kyros, Loukas, Hadjikakou, Sotiris K., Kubicki, Maciej
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246938/
https://www.ncbi.nlm.nih.gov/pubmed/22219758
http://dx.doi.org/10.1107/S1600536811040827
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author Owczarzak, Anita M.
Kyros, Loukas
Hadjikakou, Sotiris K.
Kubicki, Maciej
author_facet Owczarzak, Anita M.
Kyros, Loukas
Hadjikakou, Sotiris K.
Kubicki, Maciej
author_sort Owczarzak, Anita M.
collection PubMed
description In the title compound, [AgBr(C(18)H(15)P)(3)]·C(2)H(3)N·H(2)O, the coordination of the Ag atom is close to ideal tetra­hedral, with the three Ag—P bond lengths almost equal [2.5441 (10), 2.5523 (9) and 2.5647 (10) ° A] and the Ag—Br bond slightly longer [2.7242 (5) Å]. The coordination tetra­hedron is slightly flattened, the Ag atom is closer to the PPP plane; the P—Ag—P angles are wider than the Br—Ag—P angles. The voids in the crystal structure are filled with ordered acetonitrile solvent mol­ecules. The remaining electron density was inter­preted as a water mol­ecule, disordered over three alternative positions. Neither of the solvent mol­ecules is connected by any directional specific inter­actions with the complex.
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spelling pubmed-32469382012-01-04 Bromidotris(triphenyl­phosphane)silver acetonitrile monosolvate monohydrate Owczarzak, Anita M. Kyros, Loukas Hadjikakou, Sotiris K. Kubicki, Maciej Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [AgBr(C(18)H(15)P)(3)]·C(2)H(3)N·H(2)O, the coordination of the Ag atom is close to ideal tetra­hedral, with the three Ag—P bond lengths almost equal [2.5441 (10), 2.5523 (9) and 2.5647 (10) ° A] and the Ag—Br bond slightly longer [2.7242 (5) Å]. The coordination tetra­hedron is slightly flattened, the Ag atom is closer to the PPP plane; the P—Ag—P angles are wider than the Br—Ag—P angles. The voids in the crystal structure are filled with ordered acetonitrile solvent mol­ecules. The remaining electron density was inter­preted as a water mol­ecule, disordered over three alternative positions. Neither of the solvent mol­ecules is connected by any directional specific inter­actions with the complex. International Union of Crystallography 2011-10-08 /pmc/articles/PMC3246938/ /pubmed/22219758 http://dx.doi.org/10.1107/S1600536811040827 Text en © Owczarzak et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Owczarzak, Anita M.
Kyros, Loukas
Hadjikakou, Sotiris K.
Kubicki, Maciej
Bromidotris(triphenyl­phosphane)silver acetonitrile monosolvate monohydrate
title Bromidotris(triphenyl­phosphane)silver acetonitrile monosolvate monohydrate
title_full Bromidotris(triphenyl­phosphane)silver acetonitrile monosolvate monohydrate
title_fullStr Bromidotris(triphenyl­phosphane)silver acetonitrile monosolvate monohydrate
title_full_unstemmed Bromidotris(triphenyl­phosphane)silver acetonitrile monosolvate monohydrate
title_short Bromidotris(triphenyl­phosphane)silver acetonitrile monosolvate monohydrate
title_sort bromidotris(triphenyl­phosphane)silver acetonitrile monosolvate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246938/
https://www.ncbi.nlm.nih.gov/pubmed/22219758
http://dx.doi.org/10.1107/S1600536811040827
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