catena-Poly[[(acetato-κO)[4-(1H-pyrazol-3-yl)pyridine-κN (1)]zinc]-μ-acetato-κ(2) O:O′]

In the title compound, [Zn(CH(3)CO(2))(2)(C(8)H(7)N(3))](n), the Zn(II) atom is coordinated by one N atom from a 4-(1H-pyrazol-3-yl)pyridine ligand and three O atoms from two bridging and one terminal acetate ligands, forming a distorted tetra­hedral geometry. The bridging acetate ligands link the Z...

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Detalles Bibliográficos
Autores principales: Tan, Zheng-De, Tan, Feng-Jiao, Tan, Bo, Yi, Zhi-Wen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246942/
https://www.ncbi.nlm.nih.gov/pubmed/22219762
http://dx.doi.org/10.1107/S1600536811040190
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author Tan, Zheng-De
Tan, Feng-Jiao
Tan, Bo
Yi, Zhi-Wen
author_facet Tan, Zheng-De
Tan, Feng-Jiao
Tan, Bo
Yi, Zhi-Wen
author_sort Tan, Zheng-De
collection PubMed
description In the title compound, [Zn(CH(3)CO(2))(2)(C(8)H(7)N(3))](n), the Zn(II) atom is coordinated by one N atom from a 4-(1H-pyrazol-3-yl)pyridine ligand and three O atoms from two bridging and one terminal acetate ligands, forming a distorted tetra­hedral geometry. The bridging acetate ligands link the Zn atoms into a chain along [001]. N—H⋯O hydrogen bonds and π–π inter­actions between the pyridine and pyrazole rings [centroid–centroid distance = 3.927 (3) Å] connect the chains into a layer parallel to (011).
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spelling pubmed-32469422012-01-04 catena-Poly[[(acetato-κO)[4-(1H-pyrazol-3-yl)pyridine-κN (1)]zinc]-μ-acetato-κ(2) O:O′] Tan, Zheng-De Tan, Feng-Jiao Tan, Bo Yi, Zhi-Wen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(CH(3)CO(2))(2)(C(8)H(7)N(3))](n), the Zn(II) atom is coordinated by one N atom from a 4-(1H-pyrazol-3-yl)pyridine ligand and three O atoms from two bridging and one terminal acetate ligands, forming a distorted tetra­hedral geometry. The bridging acetate ligands link the Zn atoms into a chain along [001]. N—H⋯O hydrogen bonds and π–π inter­actions between the pyridine and pyrazole rings [centroid–centroid distance = 3.927 (3) Å] connect the chains into a layer parallel to (011). International Union of Crystallography 2011-10-12 /pmc/articles/PMC3246942/ /pubmed/22219762 http://dx.doi.org/10.1107/S1600536811040190 Text en © Tan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tan, Zheng-De
Tan, Feng-Jiao
Tan, Bo
Yi, Zhi-Wen
catena-Poly[[(acetato-κO)[4-(1H-pyrazol-3-yl)pyridine-κN (1)]zinc]-μ-acetato-κ(2) O:O′]
title catena-Poly[[(acetato-κO)[4-(1H-pyrazol-3-yl)pyridine-κN (1)]zinc]-μ-acetato-κ(2) O:O′]
title_full catena-Poly[[(acetato-κO)[4-(1H-pyrazol-3-yl)pyridine-κN (1)]zinc]-μ-acetato-κ(2) O:O′]
title_fullStr catena-Poly[[(acetato-κO)[4-(1H-pyrazol-3-yl)pyridine-κN (1)]zinc]-μ-acetato-κ(2) O:O′]
title_full_unstemmed catena-Poly[[(acetato-κO)[4-(1H-pyrazol-3-yl)pyridine-κN (1)]zinc]-μ-acetato-κ(2) O:O′]
title_short catena-Poly[[(acetato-κO)[4-(1H-pyrazol-3-yl)pyridine-κN (1)]zinc]-μ-acetato-κ(2) O:O′]
title_sort catena-poly[[(acetato-κo)[4-(1h-pyrazol-3-yl)pyridine-κn (1)]zinc]-μ-acetato-κ(2) o:o′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246942/
https://www.ncbi.nlm.nih.gov/pubmed/22219762
http://dx.doi.org/10.1107/S1600536811040190
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