Cargando…
(3-Benzoyl-1,7,7-trimethylbicyclo[2.2.1]heptan-2-olato-κ(2) O,O)bis[2-(2-pyridyl)phenyl-κ(2) C (1),N]iridium(III)
The title compound, [Ir(C(11)H(8)N)(2)(C(17)H(19)O(2))], has an octahedral coordination geometry around the Ir(III) atom, retaining the cis-C,C,trans–N,N chelate disposition of the two 2-phenylpyridine ligands. The chelate rings are nearly mutually perpendicular [the interplanar angles range from...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246943/ https://www.ncbi.nlm.nih.gov/pubmed/22219763 http://dx.doi.org/10.1107/S1600536811039262 |
Sumario: | The title compound, [Ir(C(11)H(8)N)(2)(C(17)H(19)O(2))], has an octahedral coordination geometry around the Ir(III) atom, retaining the cis-C,C,trans–N,N chelate disposition of the two 2-phenylpyridine ligands. The chelate rings are nearly mutually perpendicular [the interplanar angles range from 85.48 (17) to 89.17 (19)°]. The two 2-(2-pyridyl)phenyl ligands are approximately planar, with the plane of the phenyl ring being inclined to that of the pyridine ring by 2.3 (3) and 5.1 (3)° in the two ligands. The interplanar angle between the phenyl ring in 3-benzoyl-camphor and the IrO(2)C(3) chelate ring is 35.5 (2)°. |
---|