(3-Benzoyl-1,7,7-trimethyl­bicyclo­[2.2.1]heptan-2-olato-κ(2) O,O)bis­[2-(2-pyrid­yl)phenyl-κ(2) C (1),N]iridium(III)

The title compound, [Ir(C(11)H(8)N)(2)(C(17)H(19)O(2))], has an octa­hedral coordination geometry around the Ir(III) atom, retaining the cis-C,C,trans–N,N chelate disposition of the two 2-phenyl­pyridine ligands. The chelate rings are nearly mutually perpendicular [the inter­planar angles range from...

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Detalles Bibliográficos
Autores principales: Luo, Kaijun, Jia, Juan, Chen, Yanfang, Luo, Daibing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246943/
https://www.ncbi.nlm.nih.gov/pubmed/22219763
http://dx.doi.org/10.1107/S1600536811039262
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author Luo, Kaijun
Jia, Juan
Chen, Yanfang
Luo, Daibing
author_facet Luo, Kaijun
Jia, Juan
Chen, Yanfang
Luo, Daibing
author_sort Luo, Kaijun
collection PubMed
description The title compound, [Ir(C(11)H(8)N)(2)(C(17)H(19)O(2))], has an octa­hedral coordination geometry around the Ir(III) atom, retaining the cis-C,C,trans–N,N chelate disposition of the two 2-phenyl­pyridine ligands. The chelate rings are nearly mutually perpendicular [the inter­planar angles range from 85.48 (17) to 89.17 (19)°]. The two 2-(2-pyrid­yl)phenyl ligands are approximately planar, with the plane of the phenyl ring being inclined to that of the pyridine ring by 2.3 (3) and 5.1 (3)° in the two ligands. The inter­planar angle between the phenyl ring in 3-benzoyl-camphor and the IrO(2)C(3) chelate ring is 35.5 (2)°.
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spelling pubmed-32469432012-01-04 (3-Benzoyl-1,7,7-trimethyl­bicyclo­[2.2.1]heptan-2-olato-κ(2) O,O)bis­[2-(2-pyrid­yl)phenyl-κ(2) C (1),N]iridium(III) Luo, Kaijun Jia, Juan Chen, Yanfang Luo, Daibing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ir(C(11)H(8)N)(2)(C(17)H(19)O(2))], has an octa­hedral coordination geometry around the Ir(III) atom, retaining the cis-C,C,trans–N,N chelate disposition of the two 2-phenyl­pyridine ligands. The chelate rings are nearly mutually perpendicular [the inter­planar angles range from 85.48 (17) to 89.17 (19)°]. The two 2-(2-pyrid­yl)phenyl ligands are approximately planar, with the plane of the phenyl ring being inclined to that of the pyridine ring by 2.3 (3) and 5.1 (3)° in the two ligands. The inter­planar angle between the phenyl ring in 3-benzoyl-camphor and the IrO(2)C(3) chelate ring is 35.5 (2)°. International Union of Crystallography 2011-10-12 /pmc/articles/PMC3246943/ /pubmed/22219763 http://dx.doi.org/10.1107/S1600536811039262 Text en © Luo et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Luo, Kaijun
Jia, Juan
Chen, Yanfang
Luo, Daibing
(3-Benzoyl-1,7,7-trimethyl­bicyclo­[2.2.1]heptan-2-olato-κ(2) O,O)bis­[2-(2-pyrid­yl)phenyl-κ(2) C (1),N]iridium(III)
title (3-Benzoyl-1,7,7-trimethyl­bicyclo­[2.2.1]heptan-2-olato-κ(2) O,O)bis­[2-(2-pyrid­yl)phenyl-κ(2) C (1),N]iridium(III)
title_full (3-Benzoyl-1,7,7-trimethyl­bicyclo­[2.2.1]heptan-2-olato-κ(2) O,O)bis­[2-(2-pyrid­yl)phenyl-κ(2) C (1),N]iridium(III)
title_fullStr (3-Benzoyl-1,7,7-trimethyl­bicyclo­[2.2.1]heptan-2-olato-κ(2) O,O)bis­[2-(2-pyrid­yl)phenyl-κ(2) C (1),N]iridium(III)
title_full_unstemmed (3-Benzoyl-1,7,7-trimethyl­bicyclo­[2.2.1]heptan-2-olato-κ(2) O,O)bis­[2-(2-pyrid­yl)phenyl-κ(2) C (1),N]iridium(III)
title_short (3-Benzoyl-1,7,7-trimethyl­bicyclo­[2.2.1]heptan-2-olato-κ(2) O,O)bis­[2-(2-pyrid­yl)phenyl-κ(2) C (1),N]iridium(III)
title_sort (3-benzoyl-1,7,7-trimethyl­bicyclo­[2.2.1]heptan-2-olato-κ(2) o,o)bis­[2-(2-pyrid­yl)phenyl-κ(2) c (1),n]iridium(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246943/
https://www.ncbi.nlm.nih.gov/pubmed/22219763
http://dx.doi.org/10.1107/S1600536811039262
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