Bis[2,2′-(2-amino­ethyl­imino)­di(ethyl­ammonium)] di-μ-sulfido-bis[disulfido­stannate(IV)]

The asymmetric unit of the title compound, (C(6)H(20)N(4))(2)[Sn(2)S(6)], comprises half of a [Sn(2)S(6)](4−) anion and a diprotonated tris­(2-amino­eth­yl)amine cation. The anion lies on an inversion center, while the atoms of the cation occupy general positions. An intra­molecular N—H⋯N hydrogen b...

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Detalles Bibliográficos
Autores principales: Karey, Emma, Rosmus, Kimberly A., Aitken, Jennifer A., MacNeil, Joseph
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246945/
https://www.ncbi.nlm.nih.gov/pubmed/22219765
http://dx.doi.org/10.1107/S1600536811038657
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author Karey, Emma
Rosmus, Kimberly A.
Aitken, Jennifer A.
MacNeil, Joseph
author_facet Karey, Emma
Rosmus, Kimberly A.
Aitken, Jennifer A.
MacNeil, Joseph
author_sort Karey, Emma
collection PubMed
description The asymmetric unit of the title compound, (C(6)H(20)N(4))(2)[Sn(2)S(6)], comprises half of a [Sn(2)S(6)](4−) anion and a diprotonated tris­(2-amino­eth­yl)amine cation. The anion lies on an inversion center, while the atoms of the cation occupy general positions. An intra­molecular N—H⋯N hydrogen bond is observed in the cation. In the crystal, strong N—H⋯S hydrogen bonding between the terminal sulfur atoms of the anion and the protonated amine N atoms of the cations result in a three-dimensional network.
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spelling pubmed-32469452012-01-04 Bis[2,2′-(2-amino­ethyl­imino)­di(ethyl­ammonium)] di-μ-sulfido-bis[disulfido­stannate(IV)] Karey, Emma Rosmus, Kimberly A. Aitken, Jennifer A. MacNeil, Joseph Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(6)H(20)N(4))(2)[Sn(2)S(6)], comprises half of a [Sn(2)S(6)](4−) anion and a diprotonated tris­(2-amino­eth­yl)amine cation. The anion lies on an inversion center, while the atoms of the cation occupy general positions. An intra­molecular N—H⋯N hydrogen bond is observed in the cation. In the crystal, strong N—H⋯S hydrogen bonding between the terminal sulfur atoms of the anion and the protonated amine N atoms of the cations result in a three-dimensional network. International Union of Crystallography 2011-10-12 /pmc/articles/PMC3246945/ /pubmed/22219765 http://dx.doi.org/10.1107/S1600536811038657 Text en © Karey et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Karey, Emma
Rosmus, Kimberly A.
Aitken, Jennifer A.
MacNeil, Joseph
Bis[2,2′-(2-amino­ethyl­imino)­di(ethyl­ammonium)] di-μ-sulfido-bis[disulfido­stannate(IV)]
title Bis[2,2′-(2-amino­ethyl­imino)­di(ethyl­ammonium)] di-μ-sulfido-bis[disulfido­stannate(IV)]
title_full Bis[2,2′-(2-amino­ethyl­imino)­di(ethyl­ammonium)] di-μ-sulfido-bis[disulfido­stannate(IV)]
title_fullStr Bis[2,2′-(2-amino­ethyl­imino)­di(ethyl­ammonium)] di-μ-sulfido-bis[disulfido­stannate(IV)]
title_full_unstemmed Bis[2,2′-(2-amino­ethyl­imino)­di(ethyl­ammonium)] di-μ-sulfido-bis[disulfido­stannate(IV)]
title_short Bis[2,2′-(2-amino­ethyl­imino)­di(ethyl­ammonium)] di-μ-sulfido-bis[disulfido­stannate(IV)]
title_sort bis[2,2′-(2-amino­ethyl­imino)­di(ethyl­ammonium)] di-μ-sulfido-bis[disulfido­stannate(iv)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246945/
https://www.ncbi.nlm.nih.gov/pubmed/22219765
http://dx.doi.org/10.1107/S1600536811038657
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