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Bis(methyl xanthato)-κS;κ(2) S:S′-(triphenylphosphane-κP)palladium(II)
The title compound, [Pd(C(2)H(3)OS(2))(2)(C(18)H(15)P)], features a palladium complex with a triphenylphosphane ligand and two xanthate ligands, one of them coordinates in a bidentate and the other in a monodentate fashion, giving rise to a slightly distorted square-planar coordination of the Pd(II...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246946/ https://www.ncbi.nlm.nih.gov/pubmed/22219766 http://dx.doi.org/10.1107/S1600536811040487 |
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| author | Reyes-Martínez, Reyna Hernández-Ortega, Simón Morales-Morales, David |
| author_facet | Reyes-Martínez, Reyna Hernández-Ortega, Simón Morales-Morales, David |
| author_sort | Reyes-Martínez, Reyna |
| collection | PubMed |
| description | The title compound, [Pd(C(2)H(3)OS(2))(2)(C(18)H(15)P)], features a palladium complex with a triphenylphosphane ligand and two xanthate ligands, one of them coordinates in a bidentate and the other in a monodentate fashion, giving rise to a slightly distorted square-planar coordination of the Pd(II) ion. As a result of this difference in the coordination modes, the C—S bond lengths are different, viz. 1.687 (2) and 1.692 (2) Å in the bidentate ligand and 1.723 (2) Å in the monodentate ligand, whereas the non-coordinating S atom has a C—S distance of 1.649 (2) Å. The crystal packing is stabilized by C—H⋯O interactions. |
| format | Online Article Text |
| id | pubmed-3246946 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32469462012-01-04 Bis(methyl xanthato)-κS;κ(2) S:S′-(triphenylphosphane-κP)palladium(II) Reyes-Martínez, Reyna Hernández-Ortega, Simón Morales-Morales, David Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Pd(C(2)H(3)OS(2))(2)(C(18)H(15)P)], features a palladium complex with a triphenylphosphane ligand and two xanthate ligands, one of them coordinates in a bidentate and the other in a monodentate fashion, giving rise to a slightly distorted square-planar coordination of the Pd(II) ion. As a result of this difference in the coordination modes, the C—S bond lengths are different, viz. 1.687 (2) and 1.692 (2) Å in the bidentate ligand and 1.723 (2) Å in the monodentate ligand, whereas the non-coordinating S atom has a C—S distance of 1.649 (2) Å. The crystal packing is stabilized by C—H⋯O interactions. International Union of Crystallography 2011-10-12 /pmc/articles/PMC3246946/ /pubmed/22219766 http://dx.doi.org/10.1107/S1600536811040487 Text en © Reyes-Martínez et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Reyes-Martínez, Reyna Hernández-Ortega, Simón Morales-Morales, David Bis(methyl xanthato)-κS;κ(2) S:S′-(triphenylphosphane-κP)palladium(II) |
| title | Bis(methyl xanthato)-κS;κ(2)
S:S′-(triphenylphosphane-κP)palladium(II) |
| title_full | Bis(methyl xanthato)-κS;κ(2)
S:S′-(triphenylphosphane-κP)palladium(II) |
| title_fullStr | Bis(methyl xanthato)-κS;κ(2)
S:S′-(triphenylphosphane-κP)palladium(II) |
| title_full_unstemmed | Bis(methyl xanthato)-κS;κ(2)
S:S′-(triphenylphosphane-κP)palladium(II) |
| title_short | Bis(methyl xanthato)-κS;κ(2)
S:S′-(triphenylphosphane-κP)palladium(II) |
| title_sort | bis(methyl xanthato)-κs;κ(2)
s:s′-(triphenylphosphane-κp)palladium(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246946/ https://www.ncbi.nlm.nih.gov/pubmed/22219766 http://dx.doi.org/10.1107/S1600536811040487 |
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