Hexaaqua­cobalt(II) bis­(2,2′-sulfanediyldiacetato-κ(3) O,S,O′)cobaltate(II) tetra­hydrate

The two Co(II) atoms in the title salt, [Co(H(2)O)(6)][Co(C(4)H(4)O(4)S)(2)]·4H(2)O, exist in an octa­hedral coordination environment. In the cation, the Co atom is surrounded by six water mol­ecules, and in the anion, it is bis-O,S,O′-chelated by the thio­acetate ligands. The cations, anions and un...

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Detalles Bibliográficos
Autores principales: Wang, Huang, Gao, Shan, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246949/
https://www.ncbi.nlm.nih.gov/pubmed/22219769
http://dx.doi.org/10.1107/S1600536811040979
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author Wang, Huang
Gao, Shan
Ng, Seik Weng
author_facet Wang, Huang
Gao, Shan
Ng, Seik Weng
author_sort Wang, Huang
collection PubMed
description The two Co(II) atoms in the title salt, [Co(H(2)O)(6)][Co(C(4)H(4)O(4)S)(2)]·4H(2)O, exist in an octa­hedral coordination environment. In the cation, the Co atom is surrounded by six water mol­ecules, and in the anion, it is bis-O,S,O′-chelated by the thio­acetate ligands. The cations, anions and uncoordinated water mol­ecules are linked by O—H⋯O hydrogen bonds into a three-dimensional network.
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spelling pubmed-32469492012-01-04 Hexaaqua­cobalt(II) bis­(2,2′-sulfanediyldiacetato-κ(3) O,S,O′)cobaltate(II) tetra­hydrate Wang, Huang Gao, Shan Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The two Co(II) atoms in the title salt, [Co(H(2)O)(6)][Co(C(4)H(4)O(4)S)(2)]·4H(2)O, exist in an octa­hedral coordination environment. In the cation, the Co atom is surrounded by six water mol­ecules, and in the anion, it is bis-O,S,O′-chelated by the thio­acetate ligands. The cations, anions and uncoordinated water mol­ecules are linked by O—H⋯O hydrogen bonds into a three-dimensional network. International Union of Crystallography 2011-10-12 /pmc/articles/PMC3246949/ /pubmed/22219769 http://dx.doi.org/10.1107/S1600536811040979 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Huang
Gao, Shan
Ng, Seik Weng
Hexaaqua­cobalt(II) bis­(2,2′-sulfanediyldiacetato-κ(3) O,S,O′)cobaltate(II) tetra­hydrate
title Hexaaqua­cobalt(II) bis­(2,2′-sulfanediyldiacetato-κ(3) O,S,O′)cobaltate(II) tetra­hydrate
title_full Hexaaqua­cobalt(II) bis­(2,2′-sulfanediyldiacetato-κ(3) O,S,O′)cobaltate(II) tetra­hydrate
title_fullStr Hexaaqua­cobalt(II) bis­(2,2′-sulfanediyldiacetato-κ(3) O,S,O′)cobaltate(II) tetra­hydrate
title_full_unstemmed Hexaaqua­cobalt(II) bis­(2,2′-sulfanediyldiacetato-κ(3) O,S,O′)cobaltate(II) tetra­hydrate
title_short Hexaaqua­cobalt(II) bis­(2,2′-sulfanediyldiacetato-κ(3) O,S,O′)cobaltate(II) tetra­hydrate
title_sort hexaaqua­cobalt(ii) bis­(2,2′-sulfanediyldiacetato-κ(3) o,s,o′)cobaltate(ii) tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246949/
https://www.ncbi.nlm.nih.gov/pubmed/22219769
http://dx.doi.org/10.1107/S1600536811040979
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