catena-Poly[[bis­(μ-2-formyl-6-meth­oxy­phenolato)copper(II)sodium]-μ-nitrato]

In the title heterodinuclear complex, [CuNa(C(8)H(7)O(3))(2)(NO(3))](n), the Cu(II) ion is five-coordinated in a square-pyramidal arrangement by four atoms of two different ligand molecules in equatorial positions and one remote nitrate O atom in the apical position. The Na(+) ion is eight-coordinat...

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Detalles Bibliográficos
Autores principales: Gao, Po, Hou, Hai-Ge, Gao, Ting, Yang, Jing-Lin, Yang, Yu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246950/
https://www.ncbi.nlm.nih.gov/pubmed/22219770
http://dx.doi.org/10.1107/S1600536811040025
Descripción
Sumario:In the title heterodinuclear complex, [CuNa(C(8)H(7)O(3))(2)(NO(3))](n), the Cu(II) ion is five-coordinated in a square-pyramidal arrangement by four atoms of two different ligand molecules in equatorial positions and one remote nitrate O atom in the apical position. The Na(+) ion is eight-coordinated by four ligand O atoms and four nitrate O atoms. The ligand links the Cu(II) and Na ions, forming a layered arrangement extending parallel to (001).

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