Tetrakis(μ(3)-9-oxa-10-boraanthracen-10-olato)tetrakis[(diethyl ether)lithium]

The title compound, [Li(4)O(4)(C(12)H(8)BO)(4)(C(4)H(10)O)(4)], features a Li(4)O(4) cube. Each Li atom in the cube is additionally coordinated by a diethyl ether mol­ecule and each O atom in the cube carries a 9-oxa-10-boraanthracene residue. The crystal studied was a non-merohedral twin [twin law...

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Detalles Bibliográficos
Autores principales: Franz, Daniel, Lerner, Hans-Wolfram, Büttner, Dominik, Bolte, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246952/
https://www.ncbi.nlm.nih.gov/pubmed/22219772
http://dx.doi.org/10.1107/S1600536811041201
Descripción
Sumario:The title compound, [Li(4)O(4)(C(12)H(8)BO)(4)(C(4)H(10)O)(4)], features a Li(4)O(4) cube. Each Li atom in the cube is additionally coordinated by a diethyl ether mol­ecule and each O atom in the cube carries a 9-oxa-10-boraanthracene residue. The crystal studied was a non-merohedral twin [twin law (-1 0 0 / 0 0 1 / 0 1 0); the contribution of the major twin component refined to 0.553 (3)] emulating apparent tetra­gonal symmetry, whereas the actual crystal system is just ortho­rhom­bic.

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