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Poly[bis[μ-1,3-bis(diphenylphosphanyl)propane-κ(2) P:P′]-di-μ-thiocyanato-κ(2) S:N;κ(2) N:S-disilver(I)]
In the title coordination polymer, [Ag(2)(NCS)(2)(C(27)H(26)P(2))(2)](n), two centrosymmetrically related Ag(+) cations are linked by two thiocyanate anions into binuclear eight-membered macrocycles. The Ag⋯Ag separation within the macrocycle is 5.4400 (6) Å. The distorted tetrahedral coordination...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246955/ https://www.ncbi.nlm.nih.gov/pubmed/22219775 http://dx.doi.org/10.1107/S1600536811041250 |
| _version_ | 1782220012368429056 |
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| author | Cui, Li-Na Jiang, Yu-Han Zhou, Li-Li Jin, Qiong-Hua Zhang, Cun-Lin |
| author_facet | Cui, Li-Na Jiang, Yu-Han Zhou, Li-Li Jin, Qiong-Hua Zhang, Cun-Lin |
| author_sort | Cui, Li-Na |
| collection | PubMed |
| description | In the title coordination polymer, [Ag(2)(NCS)(2)(C(27)H(26)P(2))(2)](n), two centrosymmetrically related Ag(+) cations are linked by two thiocyanate anions into binuclear eight-membered macrocycles. The Ag⋯Ag separation within the macrocycle is 5.4400 (6) Å. The distorted tetrahedral coordination about each metal atom is completed by the P atoms of two bridging 1,3-bis(diphenylphosphanyl)propane ligands, forming polymeric ribbons parallel to the a axis. |
| format | Online Article Text |
| id | pubmed-3246955 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32469552012-01-04 Poly[bis[μ-1,3-bis(diphenylphosphanyl)propane-κ(2) P:P′]-di-μ-thiocyanato-κ(2) S:N;κ(2) N:S-disilver(I)] Cui, Li-Na Jiang, Yu-Han Zhou, Li-Li Jin, Qiong-Hua Zhang, Cun-Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Ag(2)(NCS)(2)(C(27)H(26)P(2))(2)](n), two centrosymmetrically related Ag(+) cations are linked by two thiocyanate anions into binuclear eight-membered macrocycles. The Ag⋯Ag separation within the macrocycle is 5.4400 (6) Å. The distorted tetrahedral coordination about each metal atom is completed by the P atoms of two bridging 1,3-bis(diphenylphosphanyl)propane ligands, forming polymeric ribbons parallel to the a axis. International Union of Crystallography 2011-10-12 /pmc/articles/PMC3246955/ /pubmed/22219775 http://dx.doi.org/10.1107/S1600536811041250 Text en © Cui et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Cui, Li-Na Jiang, Yu-Han Zhou, Li-Li Jin, Qiong-Hua Zhang, Cun-Lin Poly[bis[μ-1,3-bis(diphenylphosphanyl)propane-κ(2) P:P′]-di-μ-thiocyanato-κ(2) S:N;κ(2) N:S-disilver(I)] |
| title | Poly[bis[μ-1,3-bis(diphenylphosphanyl)propane-κ(2)
P:P′]-di-μ-thiocyanato-κ(2)
S:N;κ(2)
N:S-disilver(I)] |
| title_full | Poly[bis[μ-1,3-bis(diphenylphosphanyl)propane-κ(2)
P:P′]-di-μ-thiocyanato-κ(2)
S:N;κ(2)
N:S-disilver(I)] |
| title_fullStr | Poly[bis[μ-1,3-bis(diphenylphosphanyl)propane-κ(2)
P:P′]-di-μ-thiocyanato-κ(2)
S:N;κ(2)
N:S-disilver(I)] |
| title_full_unstemmed | Poly[bis[μ-1,3-bis(diphenylphosphanyl)propane-κ(2)
P:P′]-di-μ-thiocyanato-κ(2)
S:N;κ(2)
N:S-disilver(I)] |
| title_short | Poly[bis[μ-1,3-bis(diphenylphosphanyl)propane-κ(2)
P:P′]-di-μ-thiocyanato-κ(2)
S:N;κ(2)
N:S-disilver(I)] |
| title_sort | poly[bis[μ-1,3-bis(diphenylphosphanyl)propane-κ(2)
p:p′]-di-μ-thiocyanato-κ(2)
s:n;κ(2)
n:s-disilver(i)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246955/ https://www.ncbi.nlm.nih.gov/pubmed/22219775 http://dx.doi.org/10.1107/S1600536811041250 |
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