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1,1′-Bis(1-acetyl-5-methyl-1H-pyrazol-3-yl)ferrocene
The title compound, [Fe(C(11)H(11)N(2)O)(2)], crystallizes with two independent molecules in the asymmetric unit which have have different conformations. In one molecule, the two ferrocene cyclopentadienyl rings are fully eclipsed and the two pyrazole rings are syn to each other; in the other, t...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246958/ https://www.ncbi.nlm.nih.gov/pubmed/22219778 http://dx.doi.org/10.1107/S1600536811041924 |
| _version_ | 1782220013042663424 |
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| author | Zhu, Bei-Bei Shi, Yao-Cheng Shen, Wen-Bin Li, Qian-Kun |
| author_facet | Zhu, Bei-Bei Shi, Yao-Cheng Shen, Wen-Bin Li, Qian-Kun |
| author_sort | Zhu, Bei-Bei |
| collection | PubMed |
| description | The title compound, [Fe(C(11)H(11)N(2)O)(2)], crystallizes with two independent molecules in the asymmetric unit which have have different conformations. In one molecule, the two ferrocene cyclopentadienyl rings are fully eclipsed and the two pyrazole rings are syn to each other; in the other, the two cyclopentadienyl rings are synclinal and the pyrazole rings are anti. In both molecules, the acetyl group attached to the pyrazole ring is oriented away from the iron–cyclopentadienyl group of ferrocene. |
| format | Online Article Text |
| id | pubmed-3246958 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32469582012-01-04 1,1′-Bis(1-acetyl-5-methyl-1H-pyrazol-3-yl)ferrocene Zhu, Bei-Bei Shi, Yao-Cheng Shen, Wen-Bin Li, Qian-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(C(11)H(11)N(2)O)(2)], crystallizes with two independent molecules in the asymmetric unit which have have different conformations. In one molecule, the two ferrocene cyclopentadienyl rings are fully eclipsed and the two pyrazole rings are syn to each other; in the other, the two cyclopentadienyl rings are synclinal and the pyrazole rings are anti. In both molecules, the acetyl group attached to the pyrazole ring is oriented away from the iron–cyclopentadienyl group of ferrocene. International Union of Crystallography 2011-10-12 /pmc/articles/PMC3246958/ /pubmed/22219778 http://dx.doi.org/10.1107/S1600536811041924 Text en © Zhu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhu, Bei-Bei Shi, Yao-Cheng Shen, Wen-Bin Li, Qian-Kun 1,1′-Bis(1-acetyl-5-methyl-1H-pyrazol-3-yl)ferrocene |
| title | 1,1′-Bis(1-acetyl-5-methyl-1H-pyrazol-3-yl)ferrocene |
| title_full | 1,1′-Bis(1-acetyl-5-methyl-1H-pyrazol-3-yl)ferrocene |
| title_fullStr | 1,1′-Bis(1-acetyl-5-methyl-1H-pyrazol-3-yl)ferrocene |
| title_full_unstemmed | 1,1′-Bis(1-acetyl-5-methyl-1H-pyrazol-3-yl)ferrocene |
| title_short | 1,1′-Bis(1-acetyl-5-methyl-1H-pyrazol-3-yl)ferrocene |
| title_sort | 1,1′-bis(1-acetyl-5-methyl-1h-pyrazol-3-yl)ferrocene |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246958/ https://www.ncbi.nlm.nih.gov/pubmed/22219778 http://dx.doi.org/10.1107/S1600536811041924 |
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