Bis{μ-(E)-methyl 4-[(2-carbamothio­ylhydrazinyl­idene)meth­yl]benzoate-κ(2) S:S}bis­[iodido(triphenyl­phosphane-κP)copper(I)]

The title complex, [Cu(2)I(2)(C(10)H(11)N(3)O(2)S)(2)(C(18)H(15)P)(2)], is a centrosymmetric sulfur-bridged dimer of Cu(I) with PPh(3) and iodine. The Cu(I) atom shows a distorted tetra­hedral geometry, with bite angles ranging from 98.61 (2) to 120.16 (3)°. The intra­molecular Cu⋯Cu distance is 2.8...

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Detalles Bibliográficos
Autores principales: Mandal, Soumik, Nethi, Vamsidhar, Gupta, Parna
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246960/
https://www.ncbi.nlm.nih.gov/pubmed/22219780
http://dx.doi.org/10.1107/S1600536811041845
Descripción
Sumario:The title complex, [Cu(2)I(2)(C(10)H(11)N(3)O(2)S)(2)(C(18)H(15)P)(2)], is a centrosymmetric sulfur-bridged dimer of Cu(I) with PPh(3) and iodine. The Cu(I) atom shows a distorted tetra­hedral geometry, with bite angles ranging from 98.61 (2) to 120.16 (3)°. The intra­molecular Cu⋯Cu distance is 2.8228 (12) Å. The thio­semicarbazone ligand is coordinated only through the S atom. In the crystal, the complex mol­ecules are linked via inter­molecular N—H⋯O hydrogen bonds, resulting in a hydrogen-bonded chain along the b axis.

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