Bis{μ-(E)-methyl 4-[(2-carbamothio­ylhydrazinyl­idene)meth­yl]benzoate-κ(2) S:S}bis­[iodido(triphenyl­phosphane-κP)copper(I)]

The title complex, [Cu(2)I(2)(C(10)H(11)N(3)O(2)S)(2)(C(18)H(15)P)(2)], is a centrosymmetric sulfur-bridged dimer of Cu(I) with PPh(3) and iodine. The Cu(I) atom shows a distorted tetra­hedral geometry, with bite angles ranging from 98.61 (2) to 120.16 (3)°. The intra­molecular Cu⋯Cu distance is 2.8...

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Detalles Bibliográficos
Autores principales: Mandal, Soumik, Nethi, Vamsidhar, Gupta, Parna
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246960/
https://www.ncbi.nlm.nih.gov/pubmed/22219780
http://dx.doi.org/10.1107/S1600536811041845
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author Mandal, Soumik
Nethi, Vamsidhar
Gupta, Parna
author_facet Mandal, Soumik
Nethi, Vamsidhar
Gupta, Parna
author_sort Mandal, Soumik
collection PubMed
description The title complex, [Cu(2)I(2)(C(10)H(11)N(3)O(2)S)(2)(C(18)H(15)P)(2)], is a centrosymmetric sulfur-bridged dimer of Cu(I) with PPh(3) and iodine. The Cu(I) atom shows a distorted tetra­hedral geometry, with bite angles ranging from 98.61 (2) to 120.16 (3)°. The intra­molecular Cu⋯Cu distance is 2.8228 (12) Å. The thio­semicarbazone ligand is coordinated only through the S atom. In the crystal, the complex mol­ecules are linked via inter­molecular N—H⋯O hydrogen bonds, resulting in a hydrogen-bonded chain along the b axis.
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spelling pubmed-32469602012-01-04 Bis{μ-(E)-methyl 4-[(2-carbamothio­ylhydrazinyl­idene)meth­yl]benzoate-κ(2) S:S}bis­[iodido(triphenyl­phosphane-κP)copper(I)] Mandal, Soumik Nethi, Vamsidhar Gupta, Parna Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(2)I(2)(C(10)H(11)N(3)O(2)S)(2)(C(18)H(15)P)(2)], is a centrosymmetric sulfur-bridged dimer of Cu(I) with PPh(3) and iodine. The Cu(I) atom shows a distorted tetra­hedral geometry, with bite angles ranging from 98.61 (2) to 120.16 (3)°. The intra­molecular Cu⋯Cu distance is 2.8228 (12) Å. The thio­semicarbazone ligand is coordinated only through the S atom. In the crystal, the complex mol­ecules are linked via inter­molecular N—H⋯O hydrogen bonds, resulting in a hydrogen-bonded chain along the b axis. International Union of Crystallography 2011-10-12 /pmc/articles/PMC3246960/ /pubmed/22219780 http://dx.doi.org/10.1107/S1600536811041845 Text en © Mandal et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mandal, Soumik
Nethi, Vamsidhar
Gupta, Parna
Bis{μ-(E)-methyl 4-[(2-carbamothio­ylhydrazinyl­idene)meth­yl]benzoate-κ(2) S:S}bis­[iodido(triphenyl­phosphane-κP)copper(I)]
title Bis{μ-(E)-methyl 4-[(2-carbamothio­ylhydrazinyl­idene)meth­yl]benzoate-κ(2) S:S}bis­[iodido(triphenyl­phosphane-κP)copper(I)]
title_full Bis{μ-(E)-methyl 4-[(2-carbamothio­ylhydrazinyl­idene)meth­yl]benzoate-κ(2) S:S}bis­[iodido(triphenyl­phosphane-κP)copper(I)]
title_fullStr Bis{μ-(E)-methyl 4-[(2-carbamothio­ylhydrazinyl­idene)meth­yl]benzoate-κ(2) S:S}bis­[iodido(triphenyl­phosphane-κP)copper(I)]
title_full_unstemmed Bis{μ-(E)-methyl 4-[(2-carbamothio­ylhydrazinyl­idene)meth­yl]benzoate-κ(2) S:S}bis­[iodido(triphenyl­phosphane-κP)copper(I)]
title_short Bis{μ-(E)-methyl 4-[(2-carbamothio­ylhydrazinyl­idene)meth­yl]benzoate-κ(2) S:S}bis­[iodido(triphenyl­phosphane-κP)copper(I)]
title_sort bis{μ-(e)-methyl 4-[(2-carbamothio­ylhydrazinyl­idene)meth­yl]benzoate-κ(2) s:s}bis­[iodido(triphenyl­phosphane-κp)copper(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246960/
https://www.ncbi.nlm.nih.gov/pubmed/22219780
http://dx.doi.org/10.1107/S1600536811041845
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