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Bis{μ-(E)-methyl 4-[(2-carbamothioylhydrazinylidene)methyl]benzoate-κ(2) S:S}bis[iodido(triphenylphosphane-κP)copper(I)]
The title complex, [Cu(2)I(2)(C(10)H(11)N(3)O(2)S)(2)(C(18)H(15)P)(2)], is a centrosymmetric sulfur-bridged dimer of Cu(I) with PPh(3) and iodine. The Cu(I) atom shows a distorted tetrahedral geometry, with bite angles ranging from 98.61 (2) to 120.16 (3)°. The intramolecular Cu⋯Cu distance is 2.8...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246960/ https://www.ncbi.nlm.nih.gov/pubmed/22219780 http://dx.doi.org/10.1107/S1600536811041845 |