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(2-Carbamoylethyl-κ(2) C (1),O)triiodidotin(IV)

Two independent but virtually identical mol­ecules comprise the asymmetric unit of the title compound, [Sn(C(3)H(6)NO)I(3)]. The CI(3)O coordination geometry around the Sn(IV) atom is defined by a chelating carbamoylethyl ligand (C (1),O-bidentate) and three I atoms, and is based on a distorted trig...

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Autores principales: de Lima, Geraldo M., Tiekink, Edward R. T., Wardell, James L., Wardell, Solange M. S. V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246961/
https://www.ncbi.nlm.nih.gov/pubmed/22219781
http://dx.doi.org/10.1107/S1600536811041778
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author de Lima, Geraldo M.
Tiekink, Edward R. T.
Wardell, James L.
Wardell, Solange M. S. V.
author_facet de Lima, Geraldo M.
Tiekink, Edward R. T.
Wardell, James L.
Wardell, Solange M. S. V.
author_sort de Lima, Geraldo M.
collection PubMed
description Two independent but virtually identical mol­ecules comprise the asymmetric unit of the title compound, [Sn(C(3)H(6)NO)I(3)]. The CI(3)O coordination geometry around the Sn(IV) atom is defined by a chelating carbamoylethyl ligand (C (1),O-bidentate) and three I atoms, and is based on a distorted trigonal bipyramid with the carbonyl O atom occupying a position trans to one of the I atoms which forms the longer of the Sn—I bonds. The independent mol­ecules are linked via N—H⋯O hydrogen bonds, which leads to the formation on an eight-membered amide {⋯HNCO}(2) synthon. N—H⋯I hydrogen-bonding inter­actions are also present between neighbouring mol­ecules.
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spelling pubmed-32469612012-01-04 (2-Carbamoylethyl-κ(2) C (1),O)triiodidotin(IV) de Lima, Geraldo M. Tiekink, Edward R. T. Wardell, James L. Wardell, Solange M. S. V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Two independent but virtually identical mol­ecules comprise the asymmetric unit of the title compound, [Sn(C(3)H(6)NO)I(3)]. The CI(3)O coordination geometry around the Sn(IV) atom is defined by a chelating carbamoylethyl ligand (C (1),O-bidentate) and three I atoms, and is based on a distorted trigonal bipyramid with the carbonyl O atom occupying a position trans to one of the I atoms which forms the longer of the Sn—I bonds. The independent mol­ecules are linked via N—H⋯O hydrogen bonds, which leads to the formation on an eight-membered amide {⋯HNCO}(2) synthon. N—H⋯I hydrogen-bonding inter­actions are also present between neighbouring mol­ecules. International Union of Crystallography 2011-10-12 /pmc/articles/PMC3246961/ /pubmed/22219781 http://dx.doi.org/10.1107/S1600536811041778 Text en © Lima et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
de Lima, Geraldo M.
Tiekink, Edward R. T.
Wardell, James L.
Wardell, Solange M. S. V.
(2-Carbamoylethyl-κ(2) C (1),O)triiodidotin(IV)
title (2-Carbamoylethyl-κ(2) C (1),O)triiodidotin(IV)
title_full (2-Carbamoylethyl-κ(2) C (1),O)triiodidotin(IV)
title_fullStr (2-Carbamoylethyl-κ(2) C (1),O)triiodidotin(IV)
title_full_unstemmed (2-Carbamoylethyl-κ(2) C (1),O)triiodidotin(IV)
title_short (2-Carbamoylethyl-κ(2) C (1),O)triiodidotin(IV)
title_sort (2-carbamoylethyl-κ(2) c (1),o)triiodidotin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246961/
https://www.ncbi.nlm.nih.gov/pubmed/22219781
http://dx.doi.org/10.1107/S1600536811041778
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