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(2-Carbamoylethyl-κ(2) C (1),O)triiodidotin(IV)
Two independent but virtually identical molecules comprise the asymmetric unit of the title compound, [Sn(C(3)H(6)NO)I(3)]. The CI(3)O coordination geometry around the Sn(IV) atom is defined by a chelating carbamoylethyl ligand (C (1),O-bidentate) and three I atoms, and is based on a distorted trig...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246961/ https://www.ncbi.nlm.nih.gov/pubmed/22219781 http://dx.doi.org/10.1107/S1600536811041778 |
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author | de Lima, Geraldo M. Tiekink, Edward R. T. Wardell, James L. Wardell, Solange M. S. V. |
author_facet | de Lima, Geraldo M. Tiekink, Edward R. T. Wardell, James L. Wardell, Solange M. S. V. |
author_sort | de Lima, Geraldo M. |
collection | PubMed |
description | Two independent but virtually identical molecules comprise the asymmetric unit of the title compound, [Sn(C(3)H(6)NO)I(3)]. The CI(3)O coordination geometry around the Sn(IV) atom is defined by a chelating carbamoylethyl ligand (C (1),O-bidentate) and three I atoms, and is based on a distorted trigonal bipyramid with the carbonyl O atom occupying a position trans to one of the I atoms which forms the longer of the Sn—I bonds. The independent molecules are linked via N—H⋯O hydrogen bonds, which leads to the formation on an eight-membered amide {⋯HNCO}(2) synthon. N—H⋯I hydrogen-bonding interactions are also present between neighbouring molecules. |
format | Online Article Text |
id | pubmed-3246961 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32469612012-01-04 (2-Carbamoylethyl-κ(2) C (1),O)triiodidotin(IV) de Lima, Geraldo M. Tiekink, Edward R. T. Wardell, James L. Wardell, Solange M. S. V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Two independent but virtually identical molecules comprise the asymmetric unit of the title compound, [Sn(C(3)H(6)NO)I(3)]. The CI(3)O coordination geometry around the Sn(IV) atom is defined by a chelating carbamoylethyl ligand (C (1),O-bidentate) and three I atoms, and is based on a distorted trigonal bipyramid with the carbonyl O atom occupying a position trans to one of the I atoms which forms the longer of the Sn—I bonds. The independent molecules are linked via N—H⋯O hydrogen bonds, which leads to the formation on an eight-membered amide {⋯HNCO}(2) synthon. N—H⋯I hydrogen-bonding interactions are also present between neighbouring molecules. International Union of Crystallography 2011-10-12 /pmc/articles/PMC3246961/ /pubmed/22219781 http://dx.doi.org/10.1107/S1600536811041778 Text en © Lima et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers de Lima, Geraldo M. Tiekink, Edward R. T. Wardell, James L. Wardell, Solange M. S. V. (2-Carbamoylethyl-κ(2) C (1),O)triiodidotin(IV) |
title | (2-Carbamoylethyl-κ(2)
C
(1),O)triiodidotin(IV) |
title_full | (2-Carbamoylethyl-κ(2)
C
(1),O)triiodidotin(IV) |
title_fullStr | (2-Carbamoylethyl-κ(2)
C
(1),O)triiodidotin(IV) |
title_full_unstemmed | (2-Carbamoylethyl-κ(2)
C
(1),O)triiodidotin(IV) |
title_short | (2-Carbamoylethyl-κ(2)
C
(1),O)triiodidotin(IV) |
title_sort | (2-carbamoylethyl-κ(2)
c
(1),o)triiodidotin(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246961/ https://www.ncbi.nlm.nih.gov/pubmed/22219781 http://dx.doi.org/10.1107/S1600536811041778 |
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