[N′-(3-Eth­oxy-2-oxidobenzyl­idene-κO (2))-4-methyl­benzohydrazidato-κ(2) O,N′](methano­lato-κO)oxidovanadium(V)

The title oxidovanadium(V) complex, [V(C(17)H(16)N(2)O(3))(CH(3)O)O], was obtained by the reaction of 3-eth­oxy-2-hy­droxy­benzaldehyde, 4-methyl­benzohydrazide and vanadyl sulfate in methanol. The V(V) atom is coordinated by the O,N,O′-tridentate Schiff base ligand, one methano­late O atom and one...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Chen-Yi, Wu, Xiang, Cao, Feng, Yuan, Cai-Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246962/
https://www.ncbi.nlm.nih.gov/pubmed/22219782
http://dx.doi.org/10.1107/S1600536811041547
_version_ 1782220014101725184
author Wang, Chen-Yi
Wu, Xiang
Cao, Feng
Yuan, Cai-Jun
author_facet Wang, Chen-Yi
Wu, Xiang
Cao, Feng
Yuan, Cai-Jun
author_sort Wang, Chen-Yi
collection PubMed
description The title oxidovanadium(V) complex, [V(C(17)H(16)N(2)O(3))(CH(3)O)O], was obtained by the reaction of 3-eth­oxy-2-hy­droxy­benzaldehyde, 4-methyl­benzohydrazide and vanadyl sulfate in methanol. The V(V) atom is coordinated by the O,N,O′-tridentate Schiff base ligand, one methano­late O atom and one oxide O atom, forming a distorted VO(4)N square-pyramidal coordination geometry. The oxide O atom lies at the apex of the square pyramid and the N atom of the ligand and the methano­late O atom are trans. The dihedral angle between the benzene rings of the ligand is 1.8 (3)°.
format Online
Article
Text
id pubmed-3246962
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32469622012-01-04 [N′-(3-Eth­oxy-2-oxidobenzyl­idene-κO (2))-4-methyl­benzohydrazidato-κ(2) O,N′](methano­lato-κO)oxidovanadium(V) Wang, Chen-Yi Wu, Xiang Cao, Feng Yuan, Cai-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title oxidovanadium(V) complex, [V(C(17)H(16)N(2)O(3))(CH(3)O)O], was obtained by the reaction of 3-eth­oxy-2-hy­droxy­benzaldehyde, 4-methyl­benzohydrazide and vanadyl sulfate in methanol. The V(V) atom is coordinated by the O,N,O′-tridentate Schiff base ligand, one methano­late O atom and one oxide O atom, forming a distorted VO(4)N square-pyramidal coordination geometry. The oxide O atom lies at the apex of the square pyramid and the N atom of the ligand and the methano­late O atom are trans. The dihedral angle between the benzene rings of the ligand is 1.8 (3)°. International Union of Crystallography 2011-10-12 /pmc/articles/PMC3246962/ /pubmed/22219782 http://dx.doi.org/10.1107/S1600536811041547 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Chen-Yi
Wu, Xiang
Cao, Feng
Yuan, Cai-Jun
[N′-(3-Eth­oxy-2-oxidobenzyl­idene-κO (2))-4-methyl­benzohydrazidato-κ(2) O,N′](methano­lato-κO)oxidovanadium(V)
title [N′-(3-Eth­oxy-2-oxidobenzyl­idene-κO (2))-4-methyl­benzohydrazidato-κ(2) O,N′](methano­lato-κO)oxidovanadium(V)
title_full [N′-(3-Eth­oxy-2-oxidobenzyl­idene-κO (2))-4-methyl­benzohydrazidato-κ(2) O,N′](methano­lato-κO)oxidovanadium(V)
title_fullStr [N′-(3-Eth­oxy-2-oxidobenzyl­idene-κO (2))-4-methyl­benzohydrazidato-κ(2) O,N′](methano­lato-κO)oxidovanadium(V)
title_full_unstemmed [N′-(3-Eth­oxy-2-oxidobenzyl­idene-κO (2))-4-methyl­benzohydrazidato-κ(2) O,N′](methano­lato-κO)oxidovanadium(V)
title_short [N′-(3-Eth­oxy-2-oxidobenzyl­idene-κO (2))-4-methyl­benzohydrazidato-κ(2) O,N′](methano­lato-κO)oxidovanadium(V)
title_sort [n′-(3-eth­oxy-2-oxidobenzyl­idene-κo (2))-4-methyl­benzohydrazidato-κ(2) o,n′](methano­lato-κo)oxidovanadium(v)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246962/
https://www.ncbi.nlm.nih.gov/pubmed/22219782
http://dx.doi.org/10.1107/S1600536811041547
work_keys_str_mv AT wangchenyi n3ethoxy2oxidobenzylideneko24methylbenzohydrazidatok2onmethanolatokooxidovanadiumv
AT wuxiang n3ethoxy2oxidobenzylideneko24methylbenzohydrazidatok2onmethanolatokooxidovanadiumv
AT caofeng n3ethoxy2oxidobenzylideneko24methylbenzohydrazidatok2onmethanolatokooxidovanadiumv
AT yuancaijun n3ethoxy2oxidobenzylideneko24methylbenzohydrazidatok2onmethanolatokooxidovanadiumv

Ejemplares similares