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Di-μ-chlorido-bis[(2-{(E)-[(2,3-dihydroxypropyl)imino]methyl}phenolato)copper(II)] methanol monosolvate
In the title compound, [Cu(2)Cl(2)(C(10)H(12)NO(3))(2)]·CH(3)OH, each of the two Cu(II) atoms is bound to two O and one N atoms of the bis-chelating monoanionic Schiff base and two bridging chloride ligands. The metal atoms each show a distorted square-pyramidal coordination geometry. Intramolecula...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246963/ https://www.ncbi.nlm.nih.gov/pubmed/22219783 http://dx.doi.org/10.1107/S1600536811041481 |
Sumario: | In the title compound, [Cu(2)Cl(2)(C(10)H(12)NO(3))(2)]·CH(3)OH, each of the two Cu(II) atoms is bound to two O and one N atoms of the bis-chelating monoanionic Schiff base and two bridging chloride ligands. The metal atoms each show a distorted square-pyramidal coordination geometry. Intramolecular O—H⋯O hydrogen bonds occur. In the crystal, O—H⋯O hydrogen bonds join the components into a chain extending along the a axis. |
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