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Di-μ-chlorido-bis­[(2-{(E)-[(2,3-dihy­droxy­prop­yl)imino]­meth­yl}phenolato)copper(II)] methanol monosolvate

In the title compound, [Cu(2)Cl(2)(C(10)H(12)NO(3))(2)]·CH(3)OH, each of the two Cu(II) atoms is bound to two O and one N atoms of the bis-chelating monoanionic Schiff base and two bridging chloride ligands. The metal atoms each show a distorted square-pyramidal coordination geometry. Intra­molecula...

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Detalles Bibliográficos
Autor principal: Li, Yong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246963/
https://www.ncbi.nlm.nih.gov/pubmed/22219783
http://dx.doi.org/10.1107/S1600536811041481
Descripción
Sumario:In the title compound, [Cu(2)Cl(2)(C(10)H(12)NO(3))(2)]·CH(3)OH, each of the two Cu(II) atoms is bound to two O and one N atoms of the bis-chelating monoanionic Schiff base and two bridging chloride ligands. The metal atoms each show a distorted square-pyramidal coordination geometry. Intra­molecular O—H⋯O hydrogen bonds occur. In the crystal, O—H⋯O hydrogen bonds join the components into a chain extending along the a axis.