Di-μ-chlorido-bis­[(2-{(E)-[(2,3-dihy­droxy­prop­yl)imino]­meth­yl}phenolato)copper(II)] methanol monosolvate

In the title compound, [Cu(2)Cl(2)(C(10)H(12)NO(3))(2)]·CH(3)OH, each of the two Cu(II) atoms is bound to two O and one N atoms of the bis-chelating monoanionic Schiff base and two bridging chloride ligands. The metal atoms each show a distorted square-pyramidal coordination geometry. Intra­molecula...

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Detalles Bibliográficos
Autor principal: Li, Yong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246963/
https://www.ncbi.nlm.nih.gov/pubmed/22219783
http://dx.doi.org/10.1107/S1600536811041481
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author Li, Yong
author_facet Li, Yong
author_sort Li, Yong
collection PubMed
description In the title compound, [Cu(2)Cl(2)(C(10)H(12)NO(3))(2)]·CH(3)OH, each of the two Cu(II) atoms is bound to two O and one N atoms of the bis-chelating monoanionic Schiff base and two bridging chloride ligands. The metal atoms each show a distorted square-pyramidal coordination geometry. Intra­molecular O—H⋯O hydrogen bonds occur. In the crystal, O—H⋯O hydrogen bonds join the components into a chain extending along the a axis.
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spelling pubmed-32469632012-01-04 Di-μ-chlorido-bis­[(2-{(E)-[(2,3-dihy­droxy­prop­yl)imino]­meth­yl}phenolato)copper(II)] methanol monosolvate Li, Yong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(2)Cl(2)(C(10)H(12)NO(3))(2)]·CH(3)OH, each of the two Cu(II) atoms is bound to two O and one N atoms of the bis-chelating monoanionic Schiff base and two bridging chloride ligands. The metal atoms each show a distorted square-pyramidal coordination geometry. Intra­molecular O—H⋯O hydrogen bonds occur. In the crystal, O—H⋯O hydrogen bonds join the components into a chain extending along the a axis. International Union of Crystallography 2011-10-12 /pmc/articles/PMC3246963/ /pubmed/22219783 http://dx.doi.org/10.1107/S1600536811041481 Text en © Yong Li 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Yong
Di-μ-chlorido-bis­[(2-{(E)-[(2,3-dihy­droxy­prop­yl)imino]­meth­yl}phenolato)copper(II)] methanol monosolvate
title Di-μ-chlorido-bis­[(2-{(E)-[(2,3-dihy­droxy­prop­yl)imino]­meth­yl}phenolato)copper(II)] methanol monosolvate
title_full Di-μ-chlorido-bis­[(2-{(E)-[(2,3-dihy­droxy­prop­yl)imino]­meth­yl}phenolato)copper(II)] methanol monosolvate
title_fullStr Di-μ-chlorido-bis­[(2-{(E)-[(2,3-dihy­droxy­prop­yl)imino]­meth­yl}phenolato)copper(II)] methanol monosolvate
title_full_unstemmed Di-μ-chlorido-bis­[(2-{(E)-[(2,3-dihy­droxy­prop­yl)imino]­meth­yl}phenolato)copper(II)] methanol monosolvate
title_short Di-μ-chlorido-bis­[(2-{(E)-[(2,3-dihy­droxy­prop­yl)imino]­meth­yl}phenolato)copper(II)] methanol monosolvate
title_sort di-μ-chlorido-bis­[(2-{(e)-[(2,3-dihy­droxy­prop­yl)imino]­meth­yl}phenolato)copper(ii)] methanol monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246963/
https://www.ncbi.nlm.nih.gov/pubmed/22219783
http://dx.doi.org/10.1107/S1600536811041481
work_keys_str_mv AT liyong dimchloridobis2e23dihydroxypropyliminomethylphenolatocopperiimethanolmonosolvate

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