Cargando…
Poly[(μ(2)-1,3-di-4-pyridylpropane)(μ(3)-1,3-phenylenediacetato)cadmium]
In the title compound, [Cd(C(10)H(8)O(4))(C(13)H(14)N(2))](n), two symmetry-related Cd atoms are bridged by two carboxylate O atoms into a binuclear Cd(2) subunit around an inversion center. The Cd atom has a distorted pentagonal–bipyramidal environment, defined by five O atoms from three differen...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246964/ https://www.ncbi.nlm.nih.gov/pubmed/22219784 http://dx.doi.org/10.1107/S1600536811041432 |
Sumario: | In the title compound, [Cd(C(10)H(8)O(4))(C(13)H(14)N(2))](n), two symmetry-related Cd atoms are bridged by two carboxylate O atoms into a binuclear Cd(2) subunit around an inversion center. The Cd atom has a distorted pentagonal–bipyramidal environment, defined by five O atoms from three different 1,3-phenylendiacetate (1,3-pda) ligands and two N atoms from two 1,3-di-4-pyridylpropane (bpp) ligands. Each Cd(2) subunit is linked to four different Cd(2) subunits by four 1,3-pda ligands and four bpp ligands, forming a two-dimensional network with rhombic grids (12.50 × 12.50 Å(2)) extending along the ab plane. |
---|