Poly[(μ(2)-1,3-di-4-pyridyl­propane)(μ(3)-1,3-phenyl­enediacetato)­cadmium]

In the title compound, [Cd(C(10)H(8)O(4))(C(13)H(14)N(2))](n), two symmetry-related Cd atoms are bridged by two carboxyl­ate O atoms into a binuclear Cd(2) subunit around an inversion center. The Cd atom has a distorted penta­gonal–bipyramidal environment, defined by five O atoms from three differen...

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Detalles Bibliográficos
Autores principales: Liu, Dong, Li, Ni-Ya
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246964/
https://www.ncbi.nlm.nih.gov/pubmed/22219784
http://dx.doi.org/10.1107/S1600536811041432
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author Liu, Dong
Li, Ni-Ya
author_facet Liu, Dong
Li, Ni-Ya
author_sort Liu, Dong
collection PubMed
description In the title compound, [Cd(C(10)H(8)O(4))(C(13)H(14)N(2))](n), two symmetry-related Cd atoms are bridged by two carboxyl­ate O atoms into a binuclear Cd(2) subunit around an inversion center. The Cd atom has a distorted penta­gonal–bipyramidal environment, defined by five O atoms from three different 1,3-phenylendiacetate (1,3-pda) ligands and two N atoms from two 1,3-di-4-pyridyl­propane (bpp) ligands. Each Cd(2) subunit is linked to four different Cd(2) subunits by four 1,3-pda ligands and four bpp ligands, forming a two-dimensional network with rhombic grids (12.50 × 12.50 Å(2)) extending along the ab plane.
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spelling pubmed-32469642012-01-04 Poly[(μ(2)-1,3-di-4-pyridyl­propane)(μ(3)-1,3-phenyl­enediacetato)­cadmium] Liu, Dong Li, Ni-Ya Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(10)H(8)O(4))(C(13)H(14)N(2))](n), two symmetry-related Cd atoms are bridged by two carboxyl­ate O atoms into a binuclear Cd(2) subunit around an inversion center. The Cd atom has a distorted penta­gonal–bipyramidal environment, defined by five O atoms from three different 1,3-phenylendiacetate (1,3-pda) ligands and two N atoms from two 1,3-di-4-pyridyl­propane (bpp) ligands. Each Cd(2) subunit is linked to four different Cd(2) subunits by four 1,3-pda ligands and four bpp ligands, forming a two-dimensional network with rhombic grids (12.50 × 12.50 Å(2)) extending along the ab plane. International Union of Crystallography 2011-10-12 /pmc/articles/PMC3246964/ /pubmed/22219784 http://dx.doi.org/10.1107/S1600536811041432 Text en © Liu and Li 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Dong
Li, Ni-Ya
Poly[(μ(2)-1,3-di-4-pyridyl­propane)(μ(3)-1,3-phenyl­enediacetato)­cadmium]
title Poly[(μ(2)-1,3-di-4-pyridyl­propane)(μ(3)-1,3-phenyl­enediacetato)­cadmium]
title_full Poly[(μ(2)-1,3-di-4-pyridyl­propane)(μ(3)-1,3-phenyl­enediacetato)­cadmium]
title_fullStr Poly[(μ(2)-1,3-di-4-pyridyl­propane)(μ(3)-1,3-phenyl­enediacetato)­cadmium]
title_full_unstemmed Poly[(μ(2)-1,3-di-4-pyridyl­propane)(μ(3)-1,3-phenyl­enediacetato)­cadmium]
title_short Poly[(μ(2)-1,3-di-4-pyridyl­propane)(μ(3)-1,3-phenyl­enediacetato)­cadmium]
title_sort poly[(μ(2)-1,3-di-4-pyridyl­propane)(μ(3)-1,3-phenyl­enediacetato)­cadmium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246964/
https://www.ncbi.nlm.nih.gov/pubmed/22219784
http://dx.doi.org/10.1107/S1600536811041432
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