Cargando…
Diaquatetrakis(1,3-di-4-pyridylpropane-κN)manganese(II) bis(perchlorate) sesquihydrate
In the title complex, [Mn(C(13)H(14)N(2))(4)(H(2)O)(2)](ClO(4))(2)·1.5H(2)O, the Mn(II) ion is coordinated by four N atoms from four different 1,3-di-4-pyridylpropane molecules and two O atoms from two coordinated water molecules, leading to a distorted MnN(4)O(2) octahedral geometry. Each 1,3-d...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246966/ https://www.ncbi.nlm.nih.gov/pubmed/22219786 http://dx.doi.org/10.1107/S1600536811041511 |
Sumario: | In the title complex, [Mn(C(13)H(14)N(2))(4)(H(2)O)(2)](ClO(4))(2)·1.5H(2)O, the Mn(II) ion is coordinated by four N atoms from four different 1,3-di-4-pyridylpropane molecules and two O atoms from two coordinated water molecules, leading to a distorted MnN(4)O(2) octahedral geometry. Each 1,3-di-4-pyridylpropane ligand displays a monodentate coordinating mode. In the crystal, there exist O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds. The perchlorate anions and the coordinated and lattice water molecules play an important role in the formation of these hydrogen bonds. One of the two lattice water molecules shows half-occupancy. |
---|