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Diaqua­tetra­kis­(1,3-di-4-pyridylpropane-κN)­manganese(II) bis­(perchlorate) ses­qui­hydrate

In the title complex, [Mn(C(13)H(14)N(2))(4)(H(2)O)(2)](ClO(4))(2)·1.5H(2)O, the Mn(II) ion is coordinated by four N atoms from four different 1,3-di-4-pyridyl­propane mol­ecules and two O atoms from two coordinated water mol­ecules, leading to a distorted MnN(4)O(2) octa­hedral geometry. Each 1,3-d...

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Detalles Bibliográficos
Autores principales: Kuai, Hai-Wei, Cheng, Xiao-Chun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246966/
https://www.ncbi.nlm.nih.gov/pubmed/22219786
http://dx.doi.org/10.1107/S1600536811041511
Descripción
Sumario:In the title complex, [Mn(C(13)H(14)N(2))(4)(H(2)O)(2)](ClO(4))(2)·1.5H(2)O, the Mn(II) ion is coordinated by four N atoms from four different 1,3-di-4-pyridyl­propane mol­ecules and two O atoms from two coordinated water mol­ecules, leading to a distorted MnN(4)O(2) octa­hedral geometry. Each 1,3-di-4-pyridyl­propane ligand displays a monodentate coordinating mode. In the crystal, there exist O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds. The perchlorate anions and the coordinated and lattice water mol­ecules play an important role in the formation of these hydrogen bonds. One of the two lattice water molecules shows half-occupancy.