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Diaquatetrakis(1,3-di-4-pyridylpropane-κN)manganese(II) bis(perchlorate) sesquihydrate
In the title complex, [Mn(C(13)H(14)N(2))(4)(H(2)O)(2)](ClO(4))(2)·1.5H(2)O, the Mn(II) ion is coordinated by four N atoms from four different 1,3-di-4-pyridylpropane molecules and two O atoms from two coordinated water molecules, leading to a distorted MnN(4)O(2) octahedral geometry. Each 1,3-d...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246966/ https://www.ncbi.nlm.nih.gov/pubmed/22219786 http://dx.doi.org/10.1107/S1600536811041511 |
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author | Kuai, Hai-Wei Cheng, Xiao-Chun |
author_facet | Kuai, Hai-Wei Cheng, Xiao-Chun |
author_sort | Kuai, Hai-Wei |
collection | PubMed |
description | In the title complex, [Mn(C(13)H(14)N(2))(4)(H(2)O)(2)](ClO(4))(2)·1.5H(2)O, the Mn(II) ion is coordinated by four N atoms from four different 1,3-di-4-pyridylpropane molecules and two O atoms from two coordinated water molecules, leading to a distorted MnN(4)O(2) octahedral geometry. Each 1,3-di-4-pyridylpropane ligand displays a monodentate coordinating mode. In the crystal, there exist O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds. The perchlorate anions and the coordinated and lattice water molecules play an important role in the formation of these hydrogen bonds. One of the two lattice water molecules shows half-occupancy. |
format | Online Article Text |
id | pubmed-3246966 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32469662012-01-04 Diaquatetrakis(1,3-di-4-pyridylpropane-κN)manganese(II) bis(perchlorate) sesquihydrate Kuai, Hai-Wei Cheng, Xiao-Chun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(C(13)H(14)N(2))(4)(H(2)O)(2)](ClO(4))(2)·1.5H(2)O, the Mn(II) ion is coordinated by four N atoms from four different 1,3-di-4-pyridylpropane molecules and two O atoms from two coordinated water molecules, leading to a distorted MnN(4)O(2) octahedral geometry. Each 1,3-di-4-pyridylpropane ligand displays a monodentate coordinating mode. In the crystal, there exist O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds. The perchlorate anions and the coordinated and lattice water molecules play an important role in the formation of these hydrogen bonds. One of the two lattice water molecules shows half-occupancy. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3246966/ /pubmed/22219786 http://dx.doi.org/10.1107/S1600536811041511 Text en © Kuai and Cheng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Kuai, Hai-Wei Cheng, Xiao-Chun Diaquatetrakis(1,3-di-4-pyridylpropane-κN)manganese(II) bis(perchlorate) sesquihydrate |
title | Diaquatetrakis(1,3-di-4-pyridylpropane-κN)manganese(II) bis(perchlorate) sesquihydrate |
title_full | Diaquatetrakis(1,3-di-4-pyridylpropane-κN)manganese(II) bis(perchlorate) sesquihydrate |
title_fullStr | Diaquatetrakis(1,3-di-4-pyridylpropane-κN)manganese(II) bis(perchlorate) sesquihydrate |
title_full_unstemmed | Diaquatetrakis(1,3-di-4-pyridylpropane-κN)manganese(II) bis(perchlorate) sesquihydrate |
title_short | Diaquatetrakis(1,3-di-4-pyridylpropane-κN)manganese(II) bis(perchlorate) sesquihydrate |
title_sort | diaquatetrakis(1,3-di-4-pyridylpropane-κn)manganese(ii) bis(perchlorate) sesquihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246966/ https://www.ncbi.nlm.nih.gov/pubmed/22219786 http://dx.doi.org/10.1107/S1600536811041511 |
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