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Diaqua­tetra­kis­(1,3-di-4-pyridylpropane-κN)­manganese(II) bis­(perchlorate) ses­qui­hydrate

In the title complex, [Mn(C(13)H(14)N(2))(4)(H(2)O)(2)](ClO(4))(2)·1.5H(2)O, the Mn(II) ion is coordinated by four N atoms from four different 1,3-di-4-pyridyl­propane mol­ecules and two O atoms from two coordinated water mol­ecules, leading to a distorted MnN(4)O(2) octa­hedral geometry. Each 1,3-d...

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Autores principales: Kuai, Hai-Wei, Cheng, Xiao-Chun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246966/
https://www.ncbi.nlm.nih.gov/pubmed/22219786
http://dx.doi.org/10.1107/S1600536811041511
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author Kuai, Hai-Wei
Cheng, Xiao-Chun
author_facet Kuai, Hai-Wei
Cheng, Xiao-Chun
author_sort Kuai, Hai-Wei
collection PubMed
description In the title complex, [Mn(C(13)H(14)N(2))(4)(H(2)O)(2)](ClO(4))(2)·1.5H(2)O, the Mn(II) ion is coordinated by four N atoms from four different 1,3-di-4-pyridyl­propane mol­ecules and two O atoms from two coordinated water mol­ecules, leading to a distorted MnN(4)O(2) octa­hedral geometry. Each 1,3-di-4-pyridyl­propane ligand displays a monodentate coordinating mode. In the crystal, there exist O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds. The perchlorate anions and the coordinated and lattice water mol­ecules play an important role in the formation of these hydrogen bonds. One of the two lattice water molecules shows half-occupancy.
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spelling pubmed-32469662012-01-04 Diaqua­tetra­kis­(1,3-di-4-pyridylpropane-κN)­manganese(II) bis­(perchlorate) ses­qui­hydrate Kuai, Hai-Wei Cheng, Xiao-Chun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(C(13)H(14)N(2))(4)(H(2)O)(2)](ClO(4))(2)·1.5H(2)O, the Mn(II) ion is coordinated by four N atoms from four different 1,3-di-4-pyridyl­propane mol­ecules and two O atoms from two coordinated water mol­ecules, leading to a distorted MnN(4)O(2) octa­hedral geometry. Each 1,3-di-4-pyridyl­propane ligand displays a monodentate coordinating mode. In the crystal, there exist O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds. The perchlorate anions and the coordinated and lattice water mol­ecules play an important role in the formation of these hydrogen bonds. One of the two lattice water molecules shows half-occupancy. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3246966/ /pubmed/22219786 http://dx.doi.org/10.1107/S1600536811041511 Text en © Kuai and Cheng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kuai, Hai-Wei
Cheng, Xiao-Chun
Diaqua­tetra­kis­(1,3-di-4-pyridylpropane-κN)­manganese(II) bis­(perchlorate) ses­qui­hydrate
title Diaqua­tetra­kis­(1,3-di-4-pyridylpropane-κN)­manganese(II) bis­(perchlorate) ses­qui­hydrate
title_full Diaqua­tetra­kis­(1,3-di-4-pyridylpropane-κN)­manganese(II) bis­(perchlorate) ses­qui­hydrate
title_fullStr Diaqua­tetra­kis­(1,3-di-4-pyridylpropane-κN)­manganese(II) bis­(perchlorate) ses­qui­hydrate
title_full_unstemmed Diaqua­tetra­kis­(1,3-di-4-pyridylpropane-κN)­manganese(II) bis­(perchlorate) ses­qui­hydrate
title_short Diaqua­tetra­kis­(1,3-di-4-pyridylpropane-κN)­manganese(II) bis­(perchlorate) ses­qui­hydrate
title_sort diaqua­tetra­kis­(1,3-di-4-pyridylpropane-κn)­manganese(ii) bis­(perchlorate) ses­qui­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246966/
https://www.ncbi.nlm.nih.gov/pubmed/22219786
http://dx.doi.org/10.1107/S1600536811041511
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