Poly[[μ-2,2′-diethyl-1,1′-(propane-1,3-di­yl)di-1H-imidazole-κ(2) N (3):N (3′)](μ-5-hy­droxy­isophthalato-κ(2) O (1):O (3))zinc]

In the title coordination polymer, [Zn(C(8)H(4)O(5))(C(13)H(20)N(4))](n), the Zn(II) ion is coordinated by an O(2)N(2) donor set in a distorted tetra­hedral geometry. The Zn(II) ions are connected by 5-hy­droxy­isophthalate (hbdc) and 2,2′-diethyl-1,1′-(propane-1,3-di­yl)di-1H-imidazole (pbie) ligan...

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Detalles Bibliográficos
Autores principales: Liu, Ying-Ying, Wang, Chun-Jie, Yan, Yong-Sheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246967/
https://www.ncbi.nlm.nih.gov/pubmed/22219787
http://dx.doi.org/10.1107/S1600536811041456
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author Liu, Ying-Ying
Wang, Chun-Jie
Yan, Yong-Sheng
author_facet Liu, Ying-Ying
Wang, Chun-Jie
Yan, Yong-Sheng
author_sort Liu, Ying-Ying
collection PubMed
description In the title coordination polymer, [Zn(C(8)H(4)O(5))(C(13)H(20)N(4))](n), the Zn(II) ion is coordinated by an O(2)N(2) donor set in a distorted tetra­hedral geometry. The Zn(II) ions are connected by 5-hy­droxy­isophthalate (hbdc) and 2,2′-diethyl-1,1′-(propane-1,3-di­yl)di-1H-imidazole (pbie) ligands, forming a threefold inter­penetrating diamondoid framework. In the pbie ligand, one of the ethyl­imidazole groups is disordered over two positions, with a site-occupancy ratio of 0.670 (9):0.330 (9). An inter­molecular O—H⋯O hydrogen bond is formed between the hy­droxy and carboxyl­ate groups of the hbdc ligands.
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spelling pubmed-32469672012-01-04 Poly[[μ-2,2′-diethyl-1,1′-(propane-1,3-di­yl)di-1H-imidazole-κ(2) N (3):N (3′)](μ-5-hy­droxy­isophthalato-κ(2) O (1):O (3))zinc] Liu, Ying-Ying Wang, Chun-Jie Yan, Yong-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Zn(C(8)H(4)O(5))(C(13)H(20)N(4))](n), the Zn(II) ion is coordinated by an O(2)N(2) donor set in a distorted tetra­hedral geometry. The Zn(II) ions are connected by 5-hy­droxy­isophthalate (hbdc) and 2,2′-diethyl-1,1′-(propane-1,3-di­yl)di-1H-imidazole (pbie) ligands, forming a threefold inter­penetrating diamondoid framework. In the pbie ligand, one of the ethyl­imidazole groups is disordered over two positions, with a site-occupancy ratio of 0.670 (9):0.330 (9). An inter­molecular O—H⋯O hydrogen bond is formed between the hy­droxy and carboxyl­ate groups of the hbdc ligands. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3246967/ /pubmed/22219787 http://dx.doi.org/10.1107/S1600536811041456 Text en © Liu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Ying-Ying
Wang, Chun-Jie
Yan, Yong-Sheng
Poly[[μ-2,2′-diethyl-1,1′-(propane-1,3-di­yl)di-1H-imidazole-κ(2) N (3):N (3′)](μ-5-hy­droxy­isophthalato-κ(2) O (1):O (3))zinc]
title Poly[[μ-2,2′-diethyl-1,1′-(propane-1,3-di­yl)di-1H-imidazole-κ(2) N (3):N (3′)](μ-5-hy­droxy­isophthalato-κ(2) O (1):O (3))zinc]
title_full Poly[[μ-2,2′-diethyl-1,1′-(propane-1,3-di­yl)di-1H-imidazole-κ(2) N (3):N (3′)](μ-5-hy­droxy­isophthalato-κ(2) O (1):O (3))zinc]
title_fullStr Poly[[μ-2,2′-diethyl-1,1′-(propane-1,3-di­yl)di-1H-imidazole-κ(2) N (3):N (3′)](μ-5-hy­droxy­isophthalato-κ(2) O (1):O (3))zinc]
title_full_unstemmed Poly[[μ-2,2′-diethyl-1,1′-(propane-1,3-di­yl)di-1H-imidazole-κ(2) N (3):N (3′)](μ-5-hy­droxy­isophthalato-κ(2) O (1):O (3))zinc]
title_short Poly[[μ-2,2′-diethyl-1,1′-(propane-1,3-di­yl)di-1H-imidazole-κ(2) N (3):N (3′)](μ-5-hy­droxy­isophthalato-κ(2) O (1):O (3))zinc]
title_sort poly[[μ-2,2′-diethyl-1,1′-(propane-1,3-di­yl)di-1h-imidazole-κ(2) n (3):n (3′)](μ-5-hy­droxy­isophthalato-κ(2) o (1):o (3))zinc]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246967/
https://www.ncbi.nlm.nih.gov/pubmed/22219787
http://dx.doi.org/10.1107/S1600536811041456
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