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Poly[[diaquabis(μ(3)-3-carboxylato-4-hydroxybenzenesulfonato)tri-μ(2)-pyrazine-tetrasilver(I)] dihydrate]
The title coordination polymer, {[Ag(4)(C(7)H(4)O(6)S)(2)(C(4)H(4)N(2))(3)(H(2)O)(2)]·2H(2)O}(n), contains two independent Ag(I) ions. One Ag(I) ion is coordinated by one O atom from a 3-carboxylato-4-hydroxybenzenesulfonate (L) ligand, two N atoms from two pyrazine ligands and a water molecule...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246968/ https://www.ncbi.nlm.nih.gov/pubmed/22219788 http://dx.doi.org/10.1107/S1600536811041626 |
Sumario: | The title coordination polymer, {[Ag(4)(C(7)H(4)O(6)S)(2)(C(4)H(4)N(2))(3)(H(2)O)(2)]·2H(2)O}(n), contains two independent Ag(I) ions. One Ag(I) ion is coordinated by one O atom from a 3-carboxylato-4-hydroxybenzenesulfonate (L) ligand, two N atoms from two pyrazine ligands and a water molecule. The other Ag(I) ion is coordinated by two O atoms from two L ligands and one N atom from a pyrazine ligand. One of the pyrazine ligands lies on an inversion center. The L and pyrazine ligands link the Ag(I) ions into polymeric layers parallel to the ac plane. The layers are connected by intermolecular O—H⋯O hydrogen bonds. An intramolecular O—H⋯O hydrogen bond is also present in the L ligand. |
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