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Poly[[diaqua­bis­(μ(3)-3-carboxyl­ato-4-hy­droxy­benzene­sulfonato)­tri-μ(2)-pyrazine-tetra­silver(I)] dihydrate]

The title coordination polymer, {[Ag(4)(C(7)H(4)O(6)S)(2)(C(4)H(4)N(2))(3)(H(2)O)(2)]·2H(2)O}(n), contains two independent Ag(I) ions. One Ag(I) ion is coordinated by one O atom from a 3-carboxyl­ato-4-hy­droxy­benzene­sulfonate (L) ligand, two N atoms from two pyrazine ligands and a water mol­ecule...

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Detalles Bibliográficos
Autores principales: Liu, Ying-Ying, Wang, Shen-Tang, Yan, Yong-Sheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246968/
https://www.ncbi.nlm.nih.gov/pubmed/22219788
http://dx.doi.org/10.1107/S1600536811041626
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author Liu, Ying-Ying
Wang, Shen-Tang
Yan, Yong-Sheng
author_facet Liu, Ying-Ying
Wang, Shen-Tang
Yan, Yong-Sheng
author_sort Liu, Ying-Ying
collection PubMed
description The title coordination polymer, {[Ag(4)(C(7)H(4)O(6)S)(2)(C(4)H(4)N(2))(3)(H(2)O)(2)]·2H(2)O}(n), contains two independent Ag(I) ions. One Ag(I) ion is coordinated by one O atom from a 3-carboxyl­ato-4-hy­droxy­benzene­sulfonate (L) ligand, two N atoms from two pyrazine ligands and a water mol­ecule. The other Ag(I) ion is coordinated by two O atoms from two L ligands and one N atom from a pyrazine ligand. One of the pyrazine ligands lies on an inversion center. The L and pyrazine ligands link the Ag(I) ions into polymeric layers parallel to the ac plane. The layers are connected by inter­molecular O—H⋯O hydrogen bonds. An intra­molecular O—H⋯O hydrogen bond is also present in the L ligand.
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spelling pubmed-32469682012-01-04 Poly[[diaqua­bis­(μ(3)-3-carboxyl­ato-4-hy­droxy­benzene­sulfonato)­tri-μ(2)-pyrazine-tetra­silver(I)] dihydrate] Liu, Ying-Ying Wang, Shen-Tang Yan, Yong-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title coordination polymer, {[Ag(4)(C(7)H(4)O(6)S)(2)(C(4)H(4)N(2))(3)(H(2)O)(2)]·2H(2)O}(n), contains two independent Ag(I) ions. One Ag(I) ion is coordinated by one O atom from a 3-carboxyl­ato-4-hy­droxy­benzene­sulfonate (L) ligand, two N atoms from two pyrazine ligands and a water mol­ecule. The other Ag(I) ion is coordinated by two O atoms from two L ligands and one N atom from a pyrazine ligand. One of the pyrazine ligands lies on an inversion center. The L and pyrazine ligands link the Ag(I) ions into polymeric layers parallel to the ac plane. The layers are connected by inter­molecular O—H⋯O hydrogen bonds. An intra­molecular O—H⋯O hydrogen bond is also present in the L ligand. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3246968/ /pubmed/22219788 http://dx.doi.org/10.1107/S1600536811041626 Text en © Liu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Ying-Ying
Wang, Shen-Tang
Yan, Yong-Sheng
Poly[[diaqua­bis­(μ(3)-3-carboxyl­ato-4-hy­droxy­benzene­sulfonato)­tri-μ(2)-pyrazine-tetra­silver(I)] dihydrate]
title Poly[[diaqua­bis­(μ(3)-3-carboxyl­ato-4-hy­droxy­benzene­sulfonato)­tri-μ(2)-pyrazine-tetra­silver(I)] dihydrate]
title_full Poly[[diaqua­bis­(μ(3)-3-carboxyl­ato-4-hy­droxy­benzene­sulfonato)­tri-μ(2)-pyrazine-tetra­silver(I)] dihydrate]
title_fullStr Poly[[diaqua­bis­(μ(3)-3-carboxyl­ato-4-hy­droxy­benzene­sulfonato)­tri-μ(2)-pyrazine-tetra­silver(I)] dihydrate]
title_full_unstemmed Poly[[diaqua­bis­(μ(3)-3-carboxyl­ato-4-hy­droxy­benzene­sulfonato)­tri-μ(2)-pyrazine-tetra­silver(I)] dihydrate]
title_short Poly[[diaqua­bis­(μ(3)-3-carboxyl­ato-4-hy­droxy­benzene­sulfonato)­tri-μ(2)-pyrazine-tetra­silver(I)] dihydrate]
title_sort poly[[diaqua­bis­(μ(3)-3-carboxyl­ato-4-hy­droxy­benzene­sulfonato)­tri-μ(2)-pyrazine-tetra­silver(i)] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246968/
https://www.ncbi.nlm.nih.gov/pubmed/22219788
http://dx.doi.org/10.1107/S1600536811041626
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