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catena-Poly[[[(2,2′-bipyridine-κ(2) N,N′)cobalt(II)]-μ-(E)-3,3′-(but-2-ene-2,3-diyl)dibenzoato-κ(4) O,O′:O′′,O′′′] hemihydrate]
The title coordination polymer, {[Co(C(18)H(14)O(4))(C(10)H(8)N(2))]·0.5H(2)O}(n), features a helical polymeric chain that runs along the b axis. The Co atoms are chelated by the carboxylate groups of two 3,3′-(but-2-ene-2,3-diyl)dibenzoate ligands and the N atoms of a 2,2′-bipyridine ligand. The...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246969/ https://www.ncbi.nlm.nih.gov/pubmed/22219789 http://dx.doi.org/10.1107/S1600536811041699 |
| _version_ | 1782220015800418304 |
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| author | Li, Zong-Sheng Ng, Seik Weng |
| author_facet | Li, Zong-Sheng Ng, Seik Weng |
| author_sort | Li, Zong-Sheng |
| collection | PubMed |
| description | The title coordination polymer, {[Co(C(18)H(14)O(4))(C(10)H(8)N(2))]·0.5H(2)O}(n), features a helical polymeric chain that runs along the b axis. The Co atoms are chelated by the carboxylate groups of two 3,3′-(but-2-ene-2,3-diyl)dibenzoate ligands and the N atoms of a 2,2′-bipyridine ligand. The lattice water molecule is disordered about a center of inversion and is connected to the chain by an O—H⋯O hydrogen bond. The Co(II) atom shows a distorted octahedral coordination. |
| format | Online Article Text |
| id | pubmed-3246969 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32469692012-01-04 catena-Poly[[[(2,2′-bipyridine-κ(2) N,N′)cobalt(II)]-μ-(E)-3,3′-(but-2-ene-2,3-diyl)dibenzoato-κ(4) O,O′:O′′,O′′′] hemihydrate] Li, Zong-Sheng Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title coordination polymer, {[Co(C(18)H(14)O(4))(C(10)H(8)N(2))]·0.5H(2)O}(n), features a helical polymeric chain that runs along the b axis. The Co atoms are chelated by the carboxylate groups of two 3,3′-(but-2-ene-2,3-diyl)dibenzoate ligands and the N atoms of a 2,2′-bipyridine ligand. The lattice water molecule is disordered about a center of inversion and is connected to the chain by an O—H⋯O hydrogen bond. The Co(II) atom shows a distorted octahedral coordination. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3246969/ /pubmed/22219789 http://dx.doi.org/10.1107/S1600536811041699 Text en © Li and Ng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Zong-Sheng Ng, Seik Weng catena-Poly[[[(2,2′-bipyridine-κ(2) N,N′)cobalt(II)]-μ-(E)-3,3′-(but-2-ene-2,3-diyl)dibenzoato-κ(4) O,O′:O′′,O′′′] hemihydrate] |
| title |
catena-Poly[[[(2,2′-bipyridine-κ(2)
N,N′)cobalt(II)]-μ-(E)-3,3′-(but-2-ene-2,3-diyl)dibenzoato-κ(4)
O,O′:O′′,O′′′] hemihydrate] |
| title_full |
catena-Poly[[[(2,2′-bipyridine-κ(2)
N,N′)cobalt(II)]-μ-(E)-3,3′-(but-2-ene-2,3-diyl)dibenzoato-κ(4)
O,O′:O′′,O′′′] hemihydrate] |
| title_fullStr |
catena-Poly[[[(2,2′-bipyridine-κ(2)
N,N′)cobalt(II)]-μ-(E)-3,3′-(but-2-ene-2,3-diyl)dibenzoato-κ(4)
O,O′:O′′,O′′′] hemihydrate] |
| title_full_unstemmed |
catena-Poly[[[(2,2′-bipyridine-κ(2)
N,N′)cobalt(II)]-μ-(E)-3,3′-(but-2-ene-2,3-diyl)dibenzoato-κ(4)
O,O′:O′′,O′′′] hemihydrate] |
| title_short |
catena-Poly[[[(2,2′-bipyridine-κ(2)
N,N′)cobalt(II)]-μ-(E)-3,3′-(but-2-ene-2,3-diyl)dibenzoato-κ(4)
O,O′:O′′,O′′′] hemihydrate] |
| title_sort | catena-poly[[[(2,2′-bipyridine-κ(2)
n,n′)cobalt(ii)]-μ-(e)-3,3′-(but-2-ene-2,3-diyl)dibenzoato-κ(4)
o,o′:o′′,o′′′] hemihydrate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246969/ https://www.ncbi.nlm.nih.gov/pubmed/22219789 http://dx.doi.org/10.1107/S1600536811041699 |
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