The one-dimensional coordination polymer poly[tetra­kis­[(4-chloro­phen­yl)methanaminium] [cadmate-μ-cyclo­hexa­phospho­rato]]

Cyclo­hexa­phospho­ric acid (P(6)O(18)H(6)) reacts with cadmium carbonate and 4-chloro­benzyl­amine (CBA) to give the mononuclear title complex, (C(7)H(9)ClN)(4)[Cd(P(6)O(18))](n), in which the Cd(II) atom, lying on an inversion centre, has an octa­hedral coordination built of six O atoms of two cen...

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Detalles Bibliográficos
Autores principales: Abid, Sonia, Al-Deyab, S. Salem, Rzaigui, Mohamed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246971/
https://www.ncbi.nlm.nih.gov/pubmed/22219791
http://dx.doi.org/10.1107/S160053681104133X
Descripción
Sumario:Cyclo­hexa­phospho­ric acid (P(6)O(18)H(6)) reacts with cadmium carbonate and 4-chloro­benzyl­amine (CBA) to give the mononuclear title complex, (C(7)H(9)ClN)(4)[Cd(P(6)O(18))](n), in which the Cd(II) atom, lying on an inversion centre, has an octa­hedral coordination built of six O atoms of two centrosymmetric P(6)O(18) rings. Each P(6)O(18) ligand acts as a bridge, linking two Cd(II) atoms and forming an anionic coordination polymer [Cd(P(6)O(18))(4−)](n) extending along [010]. Adjacent polymeric chains are connected through N—H⋯O and C—H⋯O hydrogen bonds, generating a three-dimensional supra­molecular network.

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