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The one-dimensional coordination polymer poly[tetrakis[(4-chlorophenyl)methanaminium] [cadmate-μ-cyclohexaphosphorato]]
Cyclohexaphosphoric acid (P(6)O(18)H(6)) reacts with cadmium carbonate and 4-chlorobenzylamine (CBA) to give the mononuclear title complex, (C(7)H(9)ClN)(4)[Cd(P(6)O(18))](n), in which the Cd(II) atom, lying on an inversion centre, has an octahedral coordination built of six O atoms of two cen...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246971/ https://www.ncbi.nlm.nih.gov/pubmed/22219791 http://dx.doi.org/10.1107/S160053681104133X |
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| author | Abid, Sonia Al-Deyab, S. Salem Rzaigui, Mohamed |
| author_facet | Abid, Sonia Al-Deyab, S. Salem Rzaigui, Mohamed |
| author_sort | Abid, Sonia |
| collection | PubMed |
| description | Cyclohexaphosphoric acid (P(6)O(18)H(6)) reacts with cadmium carbonate and 4-chlorobenzylamine (CBA) to give the mononuclear title complex, (C(7)H(9)ClN)(4)[Cd(P(6)O(18))](n), in which the Cd(II) atom, lying on an inversion centre, has an octahedral coordination built of six O atoms of two centrosymmetric P(6)O(18) rings. Each P(6)O(18) ligand acts as a bridge, linking two Cd(II) atoms and forming an anionic coordination polymer [Cd(P(6)O(18))(4−)](n) extending along [010]. Adjacent polymeric chains are connected through N—H⋯O and C—H⋯O hydrogen bonds, generating a three-dimensional supramolecular network. |
| format | Online Article Text |
| id | pubmed-3246971 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32469712012-01-04 The one-dimensional coordination polymer poly[tetrakis[(4-chlorophenyl)methanaminium] [cadmate-μ-cyclohexaphosphorato]] Abid, Sonia Al-Deyab, S. Salem Rzaigui, Mohamed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Cyclohexaphosphoric acid (P(6)O(18)H(6)) reacts with cadmium carbonate and 4-chlorobenzylamine (CBA) to give the mononuclear title complex, (C(7)H(9)ClN)(4)[Cd(P(6)O(18))](n), in which the Cd(II) atom, lying on an inversion centre, has an octahedral coordination built of six O atoms of two centrosymmetric P(6)O(18) rings. Each P(6)O(18) ligand acts as a bridge, linking two Cd(II) atoms and forming an anionic coordination polymer [Cd(P(6)O(18))(4−)](n) extending along [010]. Adjacent polymeric chains are connected through N—H⋯O and C—H⋯O hydrogen bonds, generating a three-dimensional supramolecular network. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3246971/ /pubmed/22219791 http://dx.doi.org/10.1107/S160053681104133X Text en © Abid et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Abid, Sonia Al-Deyab, S. Salem Rzaigui, Mohamed The one-dimensional coordination polymer poly[tetrakis[(4-chlorophenyl)methanaminium] [cadmate-μ-cyclohexaphosphorato]] |
| title | The one-dimensional coordination polymer poly[tetrakis[(4-chlorophenyl)methanaminium] [cadmate-μ-cyclohexaphosphorato]] |
| title_full | The one-dimensional coordination polymer poly[tetrakis[(4-chlorophenyl)methanaminium] [cadmate-μ-cyclohexaphosphorato]] |
| title_fullStr | The one-dimensional coordination polymer poly[tetrakis[(4-chlorophenyl)methanaminium] [cadmate-μ-cyclohexaphosphorato]] |
| title_full_unstemmed | The one-dimensional coordination polymer poly[tetrakis[(4-chlorophenyl)methanaminium] [cadmate-μ-cyclohexaphosphorato]] |
| title_short | The one-dimensional coordination polymer poly[tetrakis[(4-chlorophenyl)methanaminium] [cadmate-μ-cyclohexaphosphorato]] |
| title_sort | one-dimensional coordination polymer poly[tetrakis[(4-chlorophenyl)methanaminium] [cadmate-μ-cyclohexaphosphorato]] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246971/ https://www.ncbi.nlm.nih.gov/pubmed/22219791 http://dx.doi.org/10.1107/S160053681104133X |
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