catena-Poly[[[bis­(4-bromo­benzoato-κO)zinc]-μ-1,2-bis­(4-pyrid­yl)ethene-κ(2) N:N′] acetonitrile monosolvate]

In the title coordination compound, {[Zn(C(7)H(4)BrO(2))(2)(C(12)H(10)N(2))]·CH(3)CN}(n), the Zn(II) atom is four-coordinated in a distorted tetra­hedral environment by two carboxyl­ate O atoms from two different 4-bromo­benzoate (bpe) ligands and two N atoms from two symmetry-related 1,2-bis­(4-pyr...

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Detalles Bibliográficos
Autores principales: Li, Ni-Ya, Sun, Deng-Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246974/
https://www.ncbi.nlm.nih.gov/pubmed/22219794
http://dx.doi.org/10.1107/S1600536811042188
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author Li, Ni-Ya
Sun, Deng-Ming
author_facet Li, Ni-Ya
Sun, Deng-Ming
author_sort Li, Ni-Ya
collection PubMed
description In the title coordination compound, {[Zn(C(7)H(4)BrO(2))(2)(C(12)H(10)N(2))]·CH(3)CN}(n), the Zn(II) atom is four-coordinated in a distorted tetra­hedral environment by two carboxyl­ate O atoms from two different 4-bromo­benzoate (bpe) ligands and two N atoms from two symmetry-related 1,2-bis­(4-pyrid­yl)ethene ligands. The Zn(II) atoms are bridged by the bpe ligands, which lie across centres of inversion, forming a zigzag chain along [001]. The void space of each unit cell is occupied by an acetonitrile solvent mol­ecule, which is connected to the complex mol­ecule by a weak C—H⋯N hydrogen bond.
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spelling pubmed-32469742012-01-04 catena-Poly[[[bis­(4-bromo­benzoato-κO)zinc]-μ-1,2-bis­(4-pyrid­yl)ethene-κ(2) N:N′] acetonitrile monosolvate] Li, Ni-Ya Sun, Deng-Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination compound, {[Zn(C(7)H(4)BrO(2))(2)(C(12)H(10)N(2))]·CH(3)CN}(n), the Zn(II) atom is four-coordinated in a distorted tetra­hedral environment by two carboxyl­ate O atoms from two different 4-bromo­benzoate (bpe) ligands and two N atoms from two symmetry-related 1,2-bis­(4-pyrid­yl)ethene ligands. The Zn(II) atoms are bridged by the bpe ligands, which lie across centres of inversion, forming a zigzag chain along [001]. The void space of each unit cell is occupied by an acetonitrile solvent mol­ecule, which is connected to the complex mol­ecule by a weak C—H⋯N hydrogen bond. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3246974/ /pubmed/22219794 http://dx.doi.org/10.1107/S1600536811042188 Text en © Li and Sun 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Ni-Ya
Sun, Deng-Ming
catena-Poly[[[bis­(4-bromo­benzoato-κO)zinc]-μ-1,2-bis­(4-pyrid­yl)ethene-κ(2) N:N′] acetonitrile monosolvate]
title catena-Poly[[[bis­(4-bromo­benzoato-κO)zinc]-μ-1,2-bis­(4-pyrid­yl)ethene-κ(2) N:N′] acetonitrile monosolvate]
title_full catena-Poly[[[bis­(4-bromo­benzoato-κO)zinc]-μ-1,2-bis­(4-pyrid­yl)ethene-κ(2) N:N′] acetonitrile monosolvate]
title_fullStr catena-Poly[[[bis­(4-bromo­benzoato-κO)zinc]-μ-1,2-bis­(4-pyrid­yl)ethene-κ(2) N:N′] acetonitrile monosolvate]
title_full_unstemmed catena-Poly[[[bis­(4-bromo­benzoato-κO)zinc]-μ-1,2-bis­(4-pyrid­yl)ethene-κ(2) N:N′] acetonitrile monosolvate]
title_short catena-Poly[[[bis­(4-bromo­benzoato-κO)zinc]-μ-1,2-bis­(4-pyrid­yl)ethene-κ(2) N:N′] acetonitrile monosolvate]
title_sort catena-poly[[[bis­(4-bromo­benzoato-κo)zinc]-μ-1,2-bis­(4-pyrid­yl)ethene-κ(2) n:n′] acetonitrile monosolvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246974/
https://www.ncbi.nlm.nih.gov/pubmed/22219794
http://dx.doi.org/10.1107/S1600536811042188
work_keys_str_mv AT liniya catenapolybis4bromobenzoatokozincm12bis4pyridylethenek2nnacetonitrilemonosolvate
AT sundengming catenapolybis4bromobenzoatokozincm12bis4pyridylethenek2nnacetonitrilemonosolvate

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