Dichlorido{N-[1-(pyrazin-2-yl)ethyl­idene-κN (1)]ethane-1,2-diamine-κ(2) N,N′}zinc

The Zn(II) atom in the title complex, [ZnCl(2)(C(8)H(12)N(4))], is coordinated by two Cl atoms and three N atoms of the N-[1-(pyrazin-2-yl)ethyl­idene]ethane-1,2-diamine ligand, and displays a distorted square-pyramidal geometry with the apical position occupied by a Cl atom. In the crystal, inter­m...

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Detalles Bibliográficos
Autores principales: Liu, Jia-Cheng, Li, Meng, Mohammed Omer, Abedelwahed Saeed, Wei, Yun, Guo, Guo-Zhe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246976/
https://www.ncbi.nlm.nih.gov/pubmed/22219796
http://dx.doi.org/10.1107/S1600536811042115
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author Liu, Jia-Cheng
Li, Meng
Mohammed Omer, Abedelwahed Saeed
Wei, Yun
Guo, Guo-Zhe
author_facet Liu, Jia-Cheng
Li, Meng
Mohammed Omer, Abedelwahed Saeed
Wei, Yun
Guo, Guo-Zhe
author_sort Liu, Jia-Cheng
collection PubMed
description The Zn(II) atom in the title complex, [ZnCl(2)(C(8)H(12)N(4))], is coordinated by two Cl atoms and three N atoms of the N-[1-(pyrazin-2-yl)ethyl­idene]ethane-1,2-diamine ligand, and displays a distorted square-pyramidal geometry with the apical position occupied by a Cl atom. In the crystal, inter­molecular N—H⋯Cl and C—H⋯Cl hydrogen bonds link the mol­ecules into a three-dimensional framework.
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spelling pubmed-32469762012-01-04 Dichlorido{N-[1-(pyrazin-2-yl)ethyl­idene-κN (1)]ethane-1,2-diamine-κ(2) N,N′}zinc Liu, Jia-Cheng Li, Meng Mohammed Omer, Abedelwahed Saeed Wei, Yun Guo, Guo-Zhe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Zn(II) atom in the title complex, [ZnCl(2)(C(8)H(12)N(4))], is coordinated by two Cl atoms and three N atoms of the N-[1-(pyrazin-2-yl)ethyl­idene]ethane-1,2-diamine ligand, and displays a distorted square-pyramidal geometry with the apical position occupied by a Cl atom. In the crystal, inter­molecular N—H⋯Cl and C—H⋯Cl hydrogen bonds link the mol­ecules into a three-dimensional framework. International Union of Crystallography 2011-10-22 /pmc/articles/PMC3246976/ /pubmed/22219796 http://dx.doi.org/10.1107/S1600536811042115 Text en © Liu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Jia-Cheng
Li, Meng
Mohammed Omer, Abedelwahed Saeed
Wei, Yun
Guo, Guo-Zhe
Dichlorido{N-[1-(pyrazin-2-yl)ethyl­idene-κN (1)]ethane-1,2-diamine-κ(2) N,N′}zinc
title Dichlorido{N-[1-(pyrazin-2-yl)ethyl­idene-κN (1)]ethane-1,2-diamine-κ(2) N,N′}zinc
title_full Dichlorido{N-[1-(pyrazin-2-yl)ethyl­idene-κN (1)]ethane-1,2-diamine-κ(2) N,N′}zinc
title_fullStr Dichlorido{N-[1-(pyrazin-2-yl)ethyl­idene-κN (1)]ethane-1,2-diamine-κ(2) N,N′}zinc
title_full_unstemmed Dichlorido{N-[1-(pyrazin-2-yl)ethyl­idene-κN (1)]ethane-1,2-diamine-κ(2) N,N′}zinc
title_short Dichlorido{N-[1-(pyrazin-2-yl)ethyl­idene-κN (1)]ethane-1,2-diamine-κ(2) N,N′}zinc
title_sort dichlorido{n-[1-(pyrazin-2-yl)ethyl­idene-κn (1)]ethane-1,2-diamine-κ(2) n,n′}zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246976/
https://www.ncbi.nlm.nih.gov/pubmed/22219796
http://dx.doi.org/10.1107/S1600536811042115
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