Dibromido{2-[(4-nitro­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}zinc(II)

In the title compound, [ZnBr(2)(C(12)H(9)N(3)O(2))], the Zn(II) ion is bonded to two Br ions and two N atoms of the diimine ligand in a distorted tetra­hedral geometry. With the exception of the Br atoms, all other atoms are disordered over two sets of sites corresponding to a 180° rotation of the m...

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Detalles Bibliográficos
Autores principales: Salehzadeh, Sadegh, Khalaj, Mehdi, Dehghanpour, Saeed, Tarmoradi, Isaac
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246977/
https://www.ncbi.nlm.nih.gov/pubmed/22219797
http://dx.doi.org/10.1107/S1600536811042231
Descripción
Sumario:In the title compound, [ZnBr(2)(C(12)H(9)N(3)O(2))], the Zn(II) ion is bonded to two Br ions and two N atoms of the diimine ligand in a distorted tetra­hedral geometry. With the exception of the Br atoms, all other atoms are disordered over two sets of sites corresponding to a 180° rotation of the mol­ecule along [[Image: see text]02]. The refined occupancies of the components are 0.809 (2) and 0.191 (2). In addition, the crystal studied was a non-merohedral twin with a refined component ratio of 0.343 (2):0.657 (2).

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