Dibromido{2-[(4-nitro­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}zinc(II)

In the title compound, [ZnBr(2)(C(12)H(9)N(3)O(2))], the Zn(II) ion is bonded to two Br ions and two N atoms of the diimine ligand in a distorted tetra­hedral geometry. With the exception of the Br atoms, all other atoms are disordered over two sets of sites corresponding to a 180° rotation of the m...

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Autores principales: Salehzadeh, Sadegh, Khalaj, Mehdi, Dehghanpour, Saeed, Tarmoradi, Isaac
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246977/
https://www.ncbi.nlm.nih.gov/pubmed/22219797
http://dx.doi.org/10.1107/S1600536811042231
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author Salehzadeh, Sadegh
Khalaj, Mehdi
Dehghanpour, Saeed
Tarmoradi, Isaac
author_facet Salehzadeh, Sadegh
Khalaj, Mehdi
Dehghanpour, Saeed
Tarmoradi, Isaac
author_sort Salehzadeh, Sadegh
collection PubMed
description In the title compound, [ZnBr(2)(C(12)H(9)N(3)O(2))], the Zn(II) ion is bonded to two Br ions and two N atoms of the diimine ligand in a distorted tetra­hedral geometry. With the exception of the Br atoms, all other atoms are disordered over two sets of sites corresponding to a 180° rotation of the mol­ecule along [[Image: see text]02]. The refined occupancies of the components are 0.809 (2) and 0.191 (2). In addition, the crystal studied was a non-merohedral twin with a refined component ratio of 0.343 (2):0.657 (2).
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spelling pubmed-32469772012-01-04 Dibromido{2-[(4-nitro­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}zinc(II) Salehzadeh, Sadegh Khalaj, Mehdi Dehghanpour, Saeed Tarmoradi, Isaac Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [ZnBr(2)(C(12)H(9)N(3)O(2))], the Zn(II) ion is bonded to two Br ions and two N atoms of the diimine ligand in a distorted tetra­hedral geometry. With the exception of the Br atoms, all other atoms are disordered over two sets of sites corresponding to a 180° rotation of the mol­ecule along [[Image: see text]02]. The refined occupancies of the components are 0.809 (2) and 0.191 (2). In addition, the crystal studied was a non-merohedral twin with a refined component ratio of 0.343 (2):0.657 (2). International Union of Crystallography 2011-10-22 /pmc/articles/PMC3246977/ /pubmed/22219797 http://dx.doi.org/10.1107/S1600536811042231 Text en © Salehzadeh et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Salehzadeh, Sadegh
Khalaj, Mehdi
Dehghanpour, Saeed
Tarmoradi, Isaac
Dibromido{2-[(4-nitro­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}zinc(II)
title Dibromido{2-[(4-nitro­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}zinc(II)
title_full Dibromido{2-[(4-nitro­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}zinc(II)
title_fullStr Dibromido{2-[(4-nitro­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}zinc(II)
title_full_unstemmed Dibromido{2-[(4-nitro­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}zinc(II)
title_short Dibromido{2-[(4-nitro­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}zinc(II)
title_sort dibromido{2-[(4-nitro­phen­yl)imino­meth­yl]pyridine-κ(2) n,n′}zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3246977/
https://www.ncbi.nlm.nih.gov/pubmed/22219797
http://dx.doi.org/10.1107/S1600536811042231
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AT tarmoradiisaac dibromido24nitrophenyliminomethylpyridinek2nnzincii

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